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Polyaniline containing W-type hexaferrite composites for microwave absorption in high-frequency applications

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Abstract

The W-type hexaferrite Ba0.85La0.15Co2Fe16O27 composite with polyaniline was synthesized by a facile route of in-situ chemical oxidative polymerization. This novel organic–inorganic composite material (PANI/Ba0.85La0.15Co2Fe16O27) can be used as a potential microwave absorber. And their microstructure, static magnetization, complex permittivity, permeability and microwave absorbing properties were subsequently investigated. Compared with pure W-type hexagonal ferrite, the composites have higher permittivity and reflection loss, which gradually increase with the increase of PANI content. The excellent microwave absorption in our experiment reached to −14.95 dB at 9.3 GHz with the layer thickness of 4 mm when the mass ratio was 0.7/0.5. More importantly, well reflection loss over a wide frequency range can be achieved by manipulating the content of PANI. The results indicated that the novel organic–inorganic materials composed of polyaniline and W-type hexagonal ferrite had an excellent microwave absorption property, and may be used as lightweight and highly effective microwave absorbers.

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Acknowledgments

This present work was financially supported by the key technology and equipment of efficient utilization of oil shale resources, No: OSR-5; and the National Science and Technology Major Projects, No: 2008ZX05018-005.

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Authors and Affiliations

  1. College of Chemistry, Jilin University, Changchun, 130026, China

    Fengying Guo, Wenwen Zi, Guijuan Ji & Shucai Gan

  2. Teaching Center of Basic Courses, Jilin University, Changchun, 130062, China

    Lianchun Zou

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  1. Fengying Guo
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  2. Wenwen Zi
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  3. Guijuan Ji
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  4. Lianchun Zou
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  5. Shucai Gan
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Correspondence to Lianchun Zou or Shucai Gan.

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Guo, F., Zi, W., Ji, G. et al. Polyaniline containing W-type hexaferrite composites for microwave absorption in high-frequency applications. J Polym Res 22, 48 (2015). https://doi.org/10.1007/s10965-015-0660-3

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