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Peculiarities of interactions between 6-aminophenalenone dye and polyurethane matrix

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Abstract

Possibility for chemical interactions of 6-aminophenalenone dye with the components of reaction mixture at the polyurethane formation was shown by means of X-ray wide angle scattering, EPR and visible spectroscopy methods. This was also confirmed by IR-spectroscopy, identifying the products of the model reaction between 6-aminophenalenone and hexamethylene diisocyanate. Observed large Stokes shift gives prospects to use efficiently the polyurethane matrix with 6-aminophenalenone as an active element in dye lasers.

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Authors and Affiliations

  1. Institute of Macromolecular Chemistry NAS of Ukraine, 48 Kharkovskoe av., Kyiv, 02160, Ukraine

    Lyudmyla Kosyanchuk, Marina Stratilat, Galyna Menzheres, Natalia Kozak & Tamara Todosiichuk

  2. Institute of Physics NAS of Ukraine, 46 Nauki av., Kyiv, 03680, Ukraine

    Tamara Bezrodna

Authors
  1. Lyudmyla Kosyanchuk
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  2. Tamara Bezrodna
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  3. Marina Stratilat
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  4. Galyna Menzheres
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  5. Natalia Kozak
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  6. Tamara Todosiichuk
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Correspondence to Tamara Bezrodna.

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Kosyanchuk, L., Bezrodna, T., Stratilat, M. et al. Peculiarities of interactions between 6-aminophenalenone dye and polyurethane matrix. J Polym Res 21, 564 (2014). https://doi.org/10.1007/s10965-014-0564-7

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  • DOI: https://doi.org/10.1007/s10965-014-0564-7

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