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Sorption behavior of polymeric gels based on alkoxysilane and aliphatic diol

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Abstract

We describe a convenient method for the synthesis of a series of cross-linked polyalkoxysilanes based on condensations of n-octyltriethoxysilane (OTES) with linear aliphatic diol monomers. The cross-linked polymers possessed moderate thermal stability and good, regenerable solvent absorption features and were effective in removing organic waste liquids from water. The polymers were characterized using Fourier transform infrared spectroscopy (FTIR), solid-state CPMAS 13C and 29Si nuclear magnetic resonance (NMR), thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), and elemental analysis. Determination of the swelling ability of the cross-linked polymers was examined by the swelling test, swelling, and desorption kinetics. The effect of the hydrophobicity of the aliphatic diol monomers on the polymer properties and solvent absorption capability was also examined.

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Acknowledgement

We thank the Scientific and Technological Research Council of Turkey–TUBITAK for the support of this work through Grant TBAG/ 111 T098.

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Authors and Affiliations

  1. Department of Chemistry, Gebze Institute of Technology, PO. Box 141, 41400, Gebze, Kocaeli, Turkey

    Koksal Karadag & Hayal Bulbul Sonmez

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  1. Koksal Karadag
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  2. Hayal Bulbul Sonmez
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Correspondence to Hayal Bulbul Sonmez.

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Karadag, K., Bulbul Sonmez, H. Sorption behavior of polymeric gels based on alkoxysilane and aliphatic diol. J Polym Res 20, 305 (2013). https://doi.org/10.1007/s10965-013-0305-3

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  • DOI: https://doi.org/10.1007/s10965-013-0305-3

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