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Hybrid copolymer latex of MMA-BA-zonyl TM-PDMS by mini-emulsion polymerization

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Abstract

Stable, coagulum free fluoro-silicone-acrylic latex (FSAL) of methyl methacrylate (MMA)-co-butyl acrylate (BA)-co-Zonyl TM-hyb-Polydimethylsiloxane (PDMS) is prepared through mini-emulsion polymerization. Apart from this, three more latexes/emulsions acrylic latex (AL) of methyl methacrylate (MMA)-co-butyl acrylate (BA), silicone-acrylic latex (SAL) of methyl methacrylate (MMA)-co-butyl acrylate (BA)-hyb- PDMS, and fluoro acrylic latex (FAL) of methyl methacrylate (MMA)-co-butyl acrylate (BA)-co-Zonyl TM are prepared for systematic understanding of the preparation and properties of the emulsions. The emulsions are prepared with almost uniform size of monomer droplets (mini-emulsions). The prepared latexes were characterized by IR, C13 NMR and 1H NMR. A systematic understanding of the effect of initial droplet size on final latex particle, the properties of the latex particles such as swelling ratio, MFFT, contact angle, distribution of particle size, rheological behavior, DSC/DMA thermograms, SEM images of the films and film topography are reported. The fluoro-silicone-acrylic latex (FSAL) exhibit, stable, low MFFT, narrow particle size distribution, and high contact angle for water, and hence it can be a great candidate as a hydrophobic binder in coating products.

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Acknowledgment

Author would like to thank to B.P. Mallik, Mr. Tapan Dhar and Dr. Biswaranjan Nayak for their kind support. Our thanks are also due to SICART and analytical lab (Asian Paints Limited) who did the characterizations in time.

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Authors and Affiliations

  1. Research & Technology Centre, Asian Paints Limited, Plot No. C3-B/1, TTCMIDC Pawne, Thane-Belapur Road, Navi Mumbai, 400703, Maharashtra, India

    Nilutpal Phukon, Chandrashekara R. Haramagatti, Parimal Jha & Vaibhav Dave

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  1. Nilutpal Phukon
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  2. Chandrashekara R. Haramagatti
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  3. Parimal Jha
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  4. Vaibhav Dave
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Correspondence to Chandrashekara R. Haramagatti or Parimal Jha.

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Phukon, N., Haramagatti, C.R., Jha, P. et al. Hybrid copolymer latex of MMA-BA-zonyl TM-PDMS by mini-emulsion polymerization. J Polym Res 20, 268 (2013). https://doi.org/10.1007/s10965-013-0268-4

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  • DOI: https://doi.org/10.1007/s10965-013-0268-4

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