Abstract
o-Benzoquinonemethacrylate QMet is prepared by the reaction between 3,6-di-tert-butyl-o-benzoquinone and monomethacrylic ethers of ethylene glycol. Free radical polymerization of this monomer allows to synthesize poly-o-benzoquinones Poly-QMet with molecular weight depending on the polymerization method and concentration of initiator. Polymerization in solution leads to polymer with 22–30 o-benzoquinone fragments in polymeric chain whereas bulk polymerization results in polymer with 110–190 o-benzoquinone fragments in polymeric chain. These polymers can be used in the preparation of metal-containing polymeric catecholate complexes. Triphenylantimony(V) polycatecholate Poly-SbCatMet is prepared by two ways – oxidative addition of SbPh3 to poly-o-quinone and polymerization of monomeric triphenylantimony catecholate SbCatMet. This polymeric catecholate Poly-SbCatMet is able to the reversible absorption of molecular oxygen on air both in solution and in thin film with conversion about 50–65 % (by NMR-spectroscopy and UV–vis data).
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This work was carried out in the framework of the Federal Target Program “Scientific and Pedagogical Specialists of Innovative Russia for 2009–2013” (Contract № GK_8460 from 31.08.2012 and “Target aspirant” agreement N14.132.21.1462 from 01.10.2012), and was financially supported by the Russian Foundation for Basic Research (N 13-03-97064-r_povolj’e_a), Russian President Grant supporting scientific schools (NSh-1113.2012.3).
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Arsenyev, M.V., Shurygina, M.P., Poddel’sky, A.I. et al. New poly-o-quinonemethacrylate and its dioxygen-active antimony-containing polymer. J Polym Res 20, 98 (2013). https://doi.org/10.1007/s10965-013-0098-4
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DOI: https://doi.org/10.1007/s10965-013-0098-4