Abstract
In this study, we used a LUMiSizer® analytical centrifuge to determine the particle dispersions and size distributions of organic/inorganic composite coatings. The centrifuge was capable of recording both the measure space and time-resolved extinction profiles (STEP™-Technology) for up to 12 samples simultaneously, making it a powerful tool for the characterization and quality control of coatings. While the variation of the light extinction curves after centrifugal segregation provided a qualitative description, a rigorous formulation can provide detailed quantitative characterization. The technique used in this study allowed demixing to be accelerated and direct quantification of the dispersibility of the coatings. Because the dispersants and binders stabilized the organic/inorganic composite coatings, the dispersibility strongly depended on their concentration. The dispersibility of the coatings increased upon increasing the dispersant concentration and decreasing the concentration of the binder. Furthermore, the inorganic particles exhibited good dispersibility, without large degrees of aggregation, in the coating dispersions. We also used the LUMiSizer® to determine the particle size distribution and shelf life of coatings; the results were comparable with those obtained using dynamic light scattering, scanning electron microscope and zeta potential analysis.
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References
Avella M, Errico ME, Martuscelli E (2001) Nano Lett 1:213
Haas KH, Schwab SA, Rose K (1999) Thin Solid Films 351:198
Wouters MEL, Wolfs DP, Linde MC, Hovens JHP, Tinnemans AHA (2004) Prog Org Coat 51:312
Wen JY, Wilkes GL (1996) Chem Mater 8:1667
Rong MZ, Zhang MQ, Shi G, Ji QL, Wetzel B, Friedrich K (2003) Tribol Int 36:697
Olson DR, Webb KK (1985) U.S. Patent 4,491,508
Sepeur S, Kunze N, Werner B, Schmidt H (1999) Thin Solid Films 351:216
Gilberts J, Tinnemans AHA (1998) RAD News 24:7
Frings S (1999) TU Eindhoven
Soloukhin VA (2003) TU Eindhoven
Misra M, Guest A, Tilley M (1998) Surf Coat Int 81:594
Beecroft LL, Ober CK (1997) Chem Mater 9:1302
Sun J, Francis LF, Francis LF (2003) J Polym Sci B Polym Phys 41:1744
Mark JE (1996) Polym Eng Sci 36:2905
Texter J, Lelental M (1999) Langmuir 15:654
Radhakrishnan S (1985) Polym Commun 26:153
Strumpler R, Glatz-Reichenbach J (1999) J Electroceram 3:329
Rao Y, Ogitani S, Kohl P, Wong CP (2002) J Appl Polym Sci 83:1084
Carmona F, Ravier J (2002) Carbon 40:151
Godovsky DY (2000) Adv Polym Sci 153:163
Chen JI, Chareonsak R, Puengpipat V, Marturunkakul S (1999) J Appl Polym Sci 74:1341
Paik U, Hackley VA, Lee HW (1999) J Am Ceram Soc 82:833
Smiechowski MF, Lvovich VF (2002) J Electroanal Chem 534:171
Lerche D (2002) J Dispers Sci Technol 23:699
Sobisch T, Lerche D (2003) Chem Prepr Server 7:198
Sobisch T, Lerche D, Detloff T, Beiser M, Erk A (2006) Filtration 6:313
Petzold G, Goltzsche C, Mende M, Schwarz S, Jaeger W (2009) J Appl Polym Sci 114:696
Detloff T, Sobisch T, Lerche D (2007) Powder Technol 174:50
Bardin M, Knight PC, Seville JPK (2004) Powder Technol 110:169
ISO 13318 (2001) Determination of the particle size distribution by centrifugal liquid sedimentation methods
Kamack HJ (1951) Anal Chem 23:844
Xiaoli J, Meijuan L (2004) China Powder Sci Technol 6:20
Karimian H, Babaluo AA (2006) Iran Polym J 15:879
ISO 22412 (2008) Particle size analysis dynamic light scattering (DLS)
Cummins PG, Staples EJ (1987) Langmuir 3:1109
van de Hulst HC (1957) Light scattering by small particles. Wiley, New York
Johansen A, Schæfer T (2001) Eur J Pharm Sci 12:297
Kornbrekke RE, Semanic P, Kirchner JT, Galic M, Bardasz EA (1998) SAE Paper, 982665
Tadros TF (1987) Actual Chim 9:270
Napper DH (1983) Polymeric stabilization of colloid dispersions. Academic, London
Tang FQ, Huang XX, Zhang YF, Guo JK (2000) Ceram Int 26:93
Ferreira JMF, Diz HMM (1992) J Eur Ceram Soc 10:59
Cao T, Yin W, Webber SE (1994) Macromolecules 27:7459
Krause B, Mende M, Pötschke P, Petzold G (2010) Carbon 48:2746
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Chiu, HT., Chang, CY., Chiang, TY. et al. Using analytical centrifugation to characterize the dispersibility and particle size distributions of organic/inorganic composite coatings. J Polym Res 18, 1587–1596 (2011). https://doi.org/10.1007/s10965-011-9563-0
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DOI: https://doi.org/10.1007/s10965-011-9563-0