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Synthesis of core-shell particles by batch emulsion polymerization of styrene and octavinyl polyhedral oligomeric silsesquioxane

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Abstract

A new composite OVPOSS-PS was prepared by batch emulsion polymerization initiated by potassium persulfate. The structure of OVPOSS-PS composite was well characterized by FTIR, 1H NMR, 29Si NMR and XRD. The results indicated that OVPOSS could be incorporated into the PS matrix by the polymerization. TEM image shown that the composite particles were in regular shape with a uniform size and have a core-shell structure. Results of XRD revealed that POSS was well dispersed in the composites. The thermal properties were investigated by DSC and TGA. The data indicated that the incorporation of POSS can apparently improve the thermal stability of PS.

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Acknowledgment

This research was kindly supported by National Natural Science Foundation of China (NO: 50673023).

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Authors and Affiliations

  1. School of Chemical and Engineering, Hefei University of Technology, Hefei, 230009, Anhui, China

    Wenping Wang, Xiaoxiao Jie, Ming Fei & Hang Jiang

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  1. Wenping Wang
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  2. Xiaoxiao Jie
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  3. Ming Fei
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  4. Hang Jiang
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Correspondence to Wenping Wang.

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Wang, W., Jie, X., Fei, M. et al. Synthesis of core-shell particles by batch emulsion polymerization of styrene and octavinyl polyhedral oligomeric silsesquioxane. J Polym Res 18, 13–17 (2011). https://doi.org/10.1007/s10965-009-9385-5

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  • DOI: https://doi.org/10.1007/s10965-009-9385-5

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