Abstract
Tris-(p-aminophenoxy)phosphineoxide, t-APPO, was prepared from 4-nitrophenol and POCl3, followed by hydrogenation. A series of polyimides prepared from t-APPO and the corresponding dianhydrides by two-stage polycondensation method was characterized by Fourier Transform Infrared Spectrometer (FTIR), GPC, thermal analysis and physical methods. Moreover, in order to check the permeation properties of the resulting polyimide film, the selectivity of the polyimide-coated electrode toward electroactive species (ascorbic acid and dopamine) was examined by means of cyclic voltammetry (CV), differential pulse voltammetry (DPV) and time-base amperometric measurement (TB) techniques. As a result, it has been found that polyimide electrode showed selective permeation for dopamine while blocking the permeation of ascorbic acid through film. Therefore, it has been claimed that phosphine oxide-containing polyimide electrode can be used as a dopamine-selective membrane in the presence of ascorbic acid.
Similar content being viewed by others
References
Mittal KL (1984) Polyimides: synthesis, characterization and applications, vol 1 & 2. Plenum, New York, pp 1–12
Bessonov MT, Koton MM, Kudryavtsev VV, Laius LA (1987) Polyimides: thermally stable polymers, 2nd edn. Consultants Bureau, New York, pp 21–27
Wilson D, Stenzenberger HD, Hergenrother PM (1990) Polyimides. Blackie, Glasgow, p 57
Ghosh MK, Mittal KL (1996) Polyimides: fundamentals and applications. Marcel Dekker, New York, p 1
Qiu Z, Zhang S (2005) Polymer 46:1693–1700
Seçkin T, Köytepe S, Özdemir İ (2003) Des Monomers Polym 6:175–185
Jeong KU, Kim JJ, Yoon TH (2001) Polymer 42:6019–6030
Meyer GW, Pak SJ, Lee YJ (1995) McGrath. Polymer 36(11):2303–2309
Lee YJ, Gungor A, Yoon TH, McGrath JE (1995) Polymer 55:165–177
Park YR, Yoon TH, Yuck JI, Lee SG (1998) Polymer (Korea) 22(6):901–907
Gülce H, Ataman İ, Gülce A, Yıldız A (2002) Enz Microb Technol 30:41–44
Gülce H, Aktaş YS, Gülce A, Yıldız A (2003) Enz Microb Technol 32:895–899
Wang H, Mu S (1999) Sens Actuators B 56:22–30
Ekinci E, Paşahan A (2004) Eur Polym J 40:1605–1608
Özden M, Ekinci E, Karagözler AE (1998) J Solid State Electrochem 2:427–143
Özden M, Ekinci E, Karagözler AE (1999) J Appl Polym Sci 71:2141–2146
Erdoğdu G, Ekinci E, Karagözler AE (2000) Polym Bull 44:195–201
Köytepe S, Paşahan A, Ekinci E, Seçkin T (2005) Eur Polym J 41:121–127
Ekinci E, Emre B, Köytepe S, Seçkin T (2005) J Polym Res 12(3):205–210
Paşahan A, Köytepe S, Ekinci E, Seçkin T (2004) Polym Bull 51:351–358
Ciszewski A, Milczarek G (1999) Anal Chem 71:1055–1061
Kaneko H, Yamada M, Aoki K (1990) Anal Sci 6:439–442
Niwa O, Morita M, Tabei H (1999) Electroanalysis 13:163–168
Gileadi E, Kirowa EE, Penciner J (1975) In interfacial electrochemistry. An experimental approach. Addison-Wesley, Reading, p 311
Myung BY, Ahn CJ, Yoon TH (2004) Polymer 45(10):3185–3193
Seçkin T, Köytepe S, Demir S, Özdemir İ, Çentinkaya B (2003) J Inorg Organomet Polym 13:223–235
Yamanaka K, Jikei M, Kakimoto MA (2000) Macromolecules 33:6937–6944
Fang J, Kita H, Okamoto KY (2000) Macromolecules 33:4639–4646
Adrova NA, Bessonov MI, Laius LA, Rudakov AP (1970) Polyimides: a new class of thermally stable polymers. Technomic Pub., Stamford, USA, pp 77–85
Bell VL, Kilzer L, Hett EM, Stokes GM (1981) J Appl Polym Sci 27:3805
Abadie MJM, Sillion B (1991) Polyimides and other high temperature polymers. Elsevier, Amsterdam, pp 1–12
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Köytepe, S., Paşahan, A., Ekinci, E. et al. Synthesis, characterization of phosphine oxide-containing polyimides and their use as selective membrane for dopamine. J Polym Res 15, 249–257 (2008). https://doi.org/10.1007/s10965-007-9165-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10965-007-9165-z