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Synthesis and characterization of poly (amide-imide-imide)s based on diacids with bulky m-chloro phenyl moiety and rigid pyridine moiety

Organosoluble poly (amide-imide-imide)

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Abstract

A series of novel aromatic diamines containing kinked m-chloro phenyl moiety was synthesized by the reaction of m-chloro benzaldehyde with 2,6-dimethyl aniline. The tetraimide diacid was synthesized by using the prepared diamine with benzophenone tetracarboxylic acid dianhydride (BPTDA) and p-amino benzoic acid. The polymers were prepared by treating the tetraimide diacid with different aromatic diamines. The structures of the monomers and polymers were identified by 1H-NMR, FTIR,13C-NMR and elemental analysis. The polymers showed excellent thermal stability, solubility and mechanical properties. Their structure–property relationship was studied by comparing these m-chloro polymers with polymers containing rigid Pyridine moiety.

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Acknowledgement

The authors are thankful to the Indian Space Research Organization (ISRO) and Council of Scientific and Industrial Research (CSIR), New Delhi for their financial help.

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Authors and Affiliations

  1. Department of Chemistry, Anna University, Chennai, 600025, India

    Sowrirajulu Bhuvana & Muthusamy Sarojadevi

Authors
  1. Sowrirajulu Bhuvana
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  2. Muthusamy Sarojadevi
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Correspondence to Muthusamy Sarojadevi.

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Bhuvana, S., Sarojadevi, M. Synthesis and characterization of poly (amide-imide-imide)s based on diacids with bulky m-chloro phenyl moiety and rigid pyridine moiety. J Polym Res 14, 261–267 (2007). https://doi.org/10.1007/s10965-007-9105-y

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  • DOI: https://doi.org/10.1007/s10965-007-9105-y

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