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Influence of Coagulant Temperature and On-Line Drawing on the Mechanical Properties and Permeation Performance of Cellulose Acetate Hollow Fibers

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Abstract

Cellulose acetate (CA) ultrafiltration hollow fibers were prepared via the dry–wet spinning technique. In the spinning process, the coagulant temperature was varied, and hence the on-line draw ratio was affected. The results revealed that the maximal draw ratio increased with the increase of coagulant temperature up to 55 ○C and then leveled off. The inner diameters, outer diameters and thickness of the hollow fiber decreased with the increase of the draw ratio. The tensile properties of the resulting hollow fibers were measured, and the breaking tensile stress increased with the increase of draw ratio. When the coagulant temperature was increased from 25 to 70 ○C, the porosity increased, the pore size was slightly enlarged in the outer skin, the hydraulic permeability increased, and the percentage of retention R decreased. In summary, by increasing the coagulant temperature, the maximal draw ratio can be increased, and hence the mass transfer properties and the other properties of drawn CA hollow fiber can be varied.

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References

  1. A. S. Jonsson and G. Tragardh, Desalination, 77, 135 (1990).

    Google Scholar 

  2. S. A. Mckelvey and W. J. Koros, J. Membr. Sci., 112, 29 (1996).

    Article  Google Scholar 

  3. I. Cabasso, E. Klein and J. K. Smith, J. Appl. Polym. Sci., 20, 2377 (1976).

    Article  Google Scholar 

  4. I. Cabasso, E. Klein and J. K. Smith, J. Appl. Polym. Sci., 21, 165 (1977).

    Article  Google Scholar 

  5. J. M. S. Henis and M. K. Tripodi, Sep. Sci. Technol., 15, 1059 (1980).

    Google Scholar 

  6. M. Sidhoum, A. Sengupa and K. K. Sirkar, AIChE J., 34, 417 (1988).

    Article  Google Scholar 

  7. S. Mok, D. J. Worsfold, A. E. Fouda, T. Matsuura, S. Wang and K. Chan, J. Membr. Sci., 100, 183 (1995).

    Article  Google Scholar 

  8. I. M. Wienk, F. H. A. Olde Scholtenhuis, Th. Van den Boomgaard and C. A. Smolders, J. Membr. Sci., 106, 233 (1995).

    Article  Google Scholar 

  9. J. J. Shieh and T. S. Chung, J. Membr. Sci., 140, 67 (1998).

    Article  Google Scholar 

  10. J. J. Qin, J. Gu and T. S. Chung, J. Membr. Sci., 182, 57 (2001).

    Article  Google Scholar 

  11. A. Idris, A. F. Ismail, M. Noorhayati and S. J. Shilton, J. Membr. Sci., 213, 45 (2003).

    Article  Google Scholar 

  12. A. Idris, A. F. Ismail, M. Noorhayati and S. J. Shilton, J. Membr. Sci., 202, 205 (2002).

    Article  Google Scholar 

  13. C. Bangxiao, Z. Yong and G. Congjie, Desalination, 146, 331 (2002).

    Article  Google Scholar 

  14. E. Sada, H. Kumazawa, J. S. Wang and M. Koizumi, J. Appl. Polym. Sci., 45, 2181 (1992).

    Article  Google Scholar 

  15. D. Gustav, S. Lothar and A. Wolfgang, U.S. Pat. 5,403,485 (1995).

  16. J. J. Qin, Y. Li, L. S. Lee and H. Lee, J. Membr. Sci., 218, 173 (2003).

    Article  Google Scholar 

  17. S. Nakatsuka, I. Nakate and T. Miyano, Desalination, 106, 55 (1996).

    Article  Google Scholar 

  18. S. A. Mckelvey, D. T. Clausi and W. J. Koros, J. Membr. Sci., 124, 223 (1997).

    Article  Google Scholar 

  19. T. S. Chung, S. K. Teoh, W. W. Y. Lau and M. P. Srinivasan, Ind. Eng. Chem., 37, 3930 (1998).

    Article  Google Scholar 

  20. O. M. Ekiner and G. Vassilatos, J. Membr. Sci., 53, 259 (1990).

    Article  Google Scholar 

  21. K. Ma, S. Sourirajan and W. W. Y. Lau, Sep. Sci. Technol., 30, 3025 (1995).

    Google Scholar 

  22. T. Liu, D. Zhang, S. Xu and S. Sourirajan, Sep. Sci. Technol., 27, 161 (1992).

    Google Scholar 

  23. J. J. Qin and T. S. Chung, J. Membr. Sci., 157, 35 (1999).

    Article  Google Scholar 

  24. T. S. Chung and E. R. Katchniski, J. Appl. Polym. Sci., 65, 1555 (1997).

    Article  Google Scholar 

  25. T. S. Chung, S. K. Teoh and X. Hu, J. Membr. Sci., 133, 161 (1998).

    Article  Google Scholar 

  26. T. S. Chung, E. R. Kafchinski and P. Foley, J. Membr. Sci., 75, 181 (1992).

    Article  Google Scholar 

  27. M. Henmi and T. Yoshioka, J. Membr. Sci., 85, 129 (1993).

    Article  Google Scholar 

  28. T. S. Chung, E. R. Kafchinski and R. Vora, J. Membr. Sci., 88, 21 (1994).

    Article  Google Scholar 

  29. X. Miao, S. Sourirajan, H. Zhang and W. W. Y. Lau, Sep. Sci. Technol., 31, 141 (1996).

    Google Scholar 

  30. T. S. Chung, Z. L. Xu and W. H. Lin, J. Appl. Polym. Sci., 72, 379 (1999).

    Article  Google Scholar 

  31. R. E. Kesting, Synthetic Polymeric Membranes, 2nd Edit., Wiley, New York, 1985, p. 290.

    Google Scholar 

  32. K.Kamada, S.Minami and K.Yoshida, U.S. Pat. 4,055,696 (1977).

  33. M. C. Yang and M. T. Chou, J. Membr. Sci., 116, 279 (1996).

    Article  Google Scholar 

  34. A. Lui and F. D. F. Talbot, J. Appl. Polym. Sci., 36, 1809 (1988).

    Article  Google Scholar 

  35. Z. L. Xu and F. A. Qusay, J. Membr. Sci., 233, 101 (2004).

    Article  Google Scholar 

  36. H. de Balmann and V.Sanchez, 32, 665 (1992).

  37. M. Dubois, K. A. Gilles, J. K. Hamilton, P. A. Rebers and F. Smith, Nature, 168, 167 (1951).

    Google Scholar 

  38. M. Dubois, K. A. Gilles, J. K. Hamilton, P. A. Rebers and F. Smith, Anal. Chem., 28, 350 (1956).

    Article  Google Scholar 

  39. Y. Abe and A. Mochzuki, J. Appl. Polym. Sci., 84, 2302 (2002).

    Article  Google Scholar 

  40. H. de Balmann, P. Aimar and V. Sanchez, J. Membr. Sci., 45, 17 (1989).

    Article  Google Scholar 

  41. H. F. Mark, S. M. Atlas and E. Cernia, Man-made Fibers, Wiley, New York, 1967.

    Google Scholar 

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Authors and Affiliations

  1. Department of Polymer Engineering, National Taiwan University of Science and Technology, Taipei, 106, Taiwan, ROC

    W. L. Chou & M. C. Yang

  2. Department of Textile Engineering, Nanya Institute of Technology, Chungli, Taoyuan, 320, Taiwan, ROC

    D. G. Yu

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  1. W. L. Chou
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  2. D. G. Yu
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  3. M. C. Yang
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Correspondence to M. C. Yang.

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Chou, W.L., Yu, D.G. & Yang, M.C. Influence of Coagulant Temperature and On-Line Drawing on the Mechanical Properties and Permeation Performance of Cellulose Acetate Hollow Fibers. J Polym Res 12, 219–229 (2005). https://doi.org/10.1007/s10965-004-3205-8

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  • DOI: https://doi.org/10.1007/s10965-004-3205-8

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