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Synthesis and Structure-Property Study of Polyarylates Derived from Bisphenols with Different Connector Groups

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Abstract

Several polyarylates were synthesized from the interfacial or high-temperature solution polycondensation reactions of four bisphenols including 2,2-bis(4-hydroxyphenyl)propane (BPA), 2,2-bis(4-hydroxyphenyl)hexafluoropropane (BPAF), 1,1-bis(4-hydroxyphenyl)-1-phenylethane (BPAP), and 1,1-bis(4-hydroxyphenyl)-1-phenyl-2,2,2-trifluoroethane (BPAPF) with various aromatic diacyl chlorides. The basic properties such as inherent viscosity, film-forming capability, crystallinity, and mechanical and thermal properties and the “structure-property” relationships of these polyarylates were investigated. The polyarylates derived from asymmetric BPAP and BPAPF had lower crystallinity and higher solubility and glass-transition temperature (Tg) than the corresponding counterparts based on symmetric BPA and BPAPF. The fluorinated polyarylates revealed higher Tg values and decomposition temperatures than the corresponding nonfluorinated polyarylates.

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Authors and Affiliations

  1. Department of Chemical Engineering, Tatung University, 40 Chungshan North Road, 3rd Section, 10451, Taipei, Taiwan, Republic of China

    Sheng-Huei Hsiao & Hsien-Wei Chiang

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  1. Sheng-Huei Hsiao
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  2. Hsien-Wei Chiang
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Correspondence to Sheng-Huei Hsiao.

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Hsiao, SH., Chiang, HW. Synthesis and Structure-Property Study of Polyarylates Derived from Bisphenols with Different Connector Groups. J Polym Res 12, 211–218 (2005). https://doi.org/10.1007/s10965-004-1870-2

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  • DOI: https://doi.org/10.1007/s10965-004-1870-2

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