Abstract
We have constructed thermodynamically consistent theory of correlations in a classical equilibrium system. The theory is based on a variational principle for thermodynamic potential, as functional of correlation functions. Both the thermodynamic potential and correlation functions are determined simultaneously from a uniform variation problem for this functional. We have offered also methods of consecutive approximations system construction for the solution of the obtained variational problem.
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Arinshteyn, E.A. Variational Principle in the Theory of Partial Distribution Functions. J Stat Phys 144, 831–845 (2011). https://doi.org/10.1007/s10955-011-0275-y
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DOI: https://doi.org/10.1007/s10955-011-0275-y