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Does the Third Law of Thermodynamics Hold in the Quantum Regime?

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Abstract

The first in a long series of papers by John T. Lewis, in collaboration with G. W. Ford and the present author, considered the problem of the most general coupling of a quantum particle to a linear passive heat bath, in the course of which they derived an exact formula for the free energy of an oscillator coupled to a heat bath in thermal equilibrium at temperature $T$. This formula, and its later extension to three dimensions to incorporate a magnetic field, has proved to be invaluable in analyzing problems in quantum thermodynamics. Here, we address the question raised in our title viz. Nernst’s third law of thermodynamics.

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PACS numbers: 05.30.-d, 05.40.-a, 05.70.-a.

The author dedicates this paper to the memory of John T. Lewis, a collaborator over two decades and a wonderful friend. He is sorely missed.

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O’connell, R.F. Does the Third Law of Thermodynamics Hold in the Quantum Regime?. J Stat Phys 124, 15–23 (2006). https://doi.org/10.1007/s10955-006-9151-6

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  • DOI: https://doi.org/10.1007/s10955-006-9151-6

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