Skip to main content

Advertisement

SpringerLink
Log in

An Overview of Molecular Interaction Studies of Binary/Ternary Liquid Mixtures with R4NI Salts Using Ultrasonic Velocity, Transport, Apparent Molar Volume, and Dielectric Constant Properties

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Due to the exceptional characteristics which result from using the ultrasonic technique, transport properties and related acoustical parameters of binary/ternary systems of different % compositions at variable temperatures with adding Et4NI to Pen4NI salts (0.14 mol·L−1) with increasing size of alkyl chain length cation, and investigated the inter-ionic interactions, molecular interactions, molecular rearrangement, molecular association, etc. Numerous theories and intermolecular interactions like dipole–dipole, dipole–induced dipole, solute–solvent, dispersive type, and H-bonding interaction between the components had shown that densities and transport properties provide a deep and meaningful insight into various interactions taking place between the liquid mixtures with salts. Such observations in the presence of specific molecular interactions of binary solutions and structural effects were analyzed based on measured and derived thermodynamical parameters.

Graphical Abstract

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Javeed, A.A., Qazi, M.O., Jean-Noel, J.Q.: Densities, apparent molar volume, expansivities, Hepler’s constant, and isobaric thermal expansion coefficients of the binary mixtures of piperazine with water, methanol, and acetone at T = 293.15 to 328.15 K. Int. J. Chem. Eng. 2018, 8689543 (2018). https://doi.org/10.1155/2018/8689534

    Article  CAS  Google Scholar 

  2. Pathak, R.N., Saxena, I., Archna, Mishra, A.K.: Study of the influence of alkyl chain cation-solvent interactions on water structure in 1,5-pentane diol–water mixture by apparent molar volume data. J. Ind. Counc. Chem. 26, 170 (2009)

    CAS  Google Scholar 

  3. Plechkova, N.V., Seddon: Applications of ionic liquids in the chemical industry. Chem. Soc. Rev. 37, 123–150 (2008). https://doi.org/10.1039/B006677J

    Article  CAS  PubMed  Google Scholar 

  4. Attri, P., Venkatesu, P.: Thermodynamic characterization of the biocompatible ionic liquid effects on protein model compounds and their functional groups. Phys. Chem. Chem. Phys. 13, 6566–6575 (2011). https://doi.org/10.1039/C0CP02768E

    Article  CAS  PubMed  Google Scholar 

  5. Sechul, C., Judi, G., Manikandan, M.: A consolidative synopsis of the MALDI-TOF MS accomplishments for the rapid diagnosis of microbial plant disease pathogens. Phys. Proc. 3, 35–46 (2010). https://doi.org/10.1016/j.trac.2022.116713

    Article  CAS  Google Scholar 

  6. Zade, S.D.: Study of molecular interactions of coumaran-3-ones in polar and non polar solvents using ultrasonic interferometer. Rasayan J. Chem. 4, 620–629 (2011)

    CAS  Google Scholar 

  7. Frank, H.S.: Single ion activities and ion–solvent interaction in dilute aqueous solutions. J. Phys. Chem. 67, 1554–1558 (1963). https://doi.org/10.1021/j100801a037

    Article  CAS  Google Scholar 

  8. Pathak, R.N., Saxena, I., Archna, N., Kumar, R., Singh, N.: Study of the influence of alkyl chain cation-solvent interactions on the slope of ϕv vs C curves in 1,5-pentane diol–DMF solvent mixtures by apparent molar volume measurements. Chem. Sci. Trans. 3, 87–92 (2014)

    Google Scholar 

  9. Crossley, J., Tay, S.P., Waker, S.: Evaluation of relaxation parameters from dielectric data. Adv. Mol. Relax. Process 6, 69–78 (1974). https://doi.org/10.1016/0001-8716(74)80017-9

    Article  CAS  Google Scholar 

  10. Thirunavukkarasu, M., Kanagathara, N.: Ultrasonic studies on non-aqueous solutions of toluene in nitrobenze. Int. J. ChemTech. Res. 4, 459–463 (2012)

    CAS  Google Scholar 

  11. Neves, C.M.S.S., Kurnia, K.A., Coutinho, J.A.P., Marrucho, I.M., Lopes, J.N.C., Freire, M.G., Rebelo, L.P.N.: Systematic study of the thermophysical properties of imidazolium-based ionic liquids with cyano-functionalized anions. J. Phys. Chem. B 117, 10271–10283 (2013). https://doi.org/10.1021/jp405913b

    Article  CAS  PubMed  Google Scholar 

  12. Sengwa, R.J., Sankhla, S., Khatri, V., Choudhary, S.: Static permittivity and molecular interactions in binary mixtures of ethanolamine with alcohols and amides. Fluid Phase Equilib. 293, 137–140 (2010). https://doi.org/10.1016/j.fluid.2010.02.038

    Article  CAS  Google Scholar 

  13. Lux, A., Stockhausen, M.: A dielectric relaxation study of some liquid dihydric alcohols and their mixtures with water. Phys. Chem. Liq. 26, 67–83 (1993). https://doi.org/10.1080/00319109308030374

    Article  CAS  Google Scholar 

  14. Rana, V.A., Chaube, H.A.: Relative permittivity, density, viscosity, refractive index and ultrasonic velocity of binary mixture of ethylene glycol monophenyl ether and 1-hexanol at different temperatures. J. Mol. Liq. 187, 66–73 (2013). https://doi.org/10.1016/j.molliq.2013.06.007

    Article  CAS  Google Scholar 

  15. Saxena, I., Pathak, R.N., Kumar, V., Devi, R.: Introduction of ultrasonic interferometer and experimental techniques for determination of ultrasonic velocity, density, viscosity and various thermodynamic parameters. Int. J. Appl. Res. 9, 562–569 (2015)

    Google Scholar 

  16. Pathak, R.N., Saxena, I.: Magnetic float densitometer—a modified version. Ind. J. Eng. Mat. Sci. 5, 278–284 (1998)

    Google Scholar 

  17. Dutka, A.P.: Instrument Society of America, Pulp and Paper Industry Division Proc. TAPPI Process Control, Electrical and Instrumentation Conf. (ISA), March (1997)

  18. Saxena, I., Kumar, V.: Automatic version of Ostwald viscometer for conducting liquids. Instr. Exp. Tech. 64, 327–330 (2021). https://doi.org/10.1134/S0020441221010322

    Article  Google Scholar 

  19. Nikkam, P.S., Hasan, M.: Ultrasonic velocity and adiabatic compressibility of monochloroacetic acid in aqueous ethanol at various temperatures. J. Chem. Eng. Data 88, 165–169 (1988). https://doi.org/10.1021/je00052a032

    Article  Google Scholar 

  20. Naik, R.R., Bawankar, S.V.: Acoustical studies of molecular interactions in the solution of methyl cobalamine drug at different temperatures and concentrations. Orbital 6, 87–92 (2014). https://doi.org/10.17807/orbital.v6i2.585

    Article  Google Scholar 

Citation metadata

  1. Venkateswarlu, P., Raman, G.K.: Ultrasonic studies in binary mixtures of 1–2-dibromoethane with alcohols at 30315 K. J. Pure Appl. Ultrasonic. 7, 27–30 (1985). https://doi.org/10.1080/00319109008036408

    Article  Google Scholar 

  2. Reddy, R.K., Murthy, R.S., Moorthy, R.L.: J. Acoustic Soc. Ind. 19, 22 (1991)

    Google Scholar 

  3. Kumar, N., Vijaya, B., Sadasiva, A.R., Chowdoji, K.R.: J. Acoustic. Soc. Ind. 28, 297–300 (2000)

    Google Scholar 

  4. Ali, A., Nainand, A.K., Kamil, M.: Physico-chemical studies of non-aqueous binary liquid mixtures at various temperatures. Thermochim. Acta 274, 209–221 (1996). https://doi.org/10.1016/0040-6031(95)02719-X

    Article  CAS  Google Scholar 

  5. Singh, R.P., Reddy, G.V., Majumdar, S., Singh, Y.P.: Ultrasonic velocities and Rao and Wada formulism in polymer solutions. J. Pure Appl. Ultrasonic. 5, 52–54 (1983)

    Google Scholar 

  6. Maurya, V.N., Kaur, A.R., Maurya, A.K., Gautam, R.A.: Measurement of ultrasonic velocity, density, viscosity and refractive index of liquids using experimental techniques. World Sci. J. 2, 27–48 (2013)

    Google Scholar 

  7. Shukla, R.K., Kumar, A., Shukla, A., Srivastava, K.: Density, ultrasonic velocity, surface tension, excess volume and viscosity of quaternary fluid solutions. J. Mol. Liq. 140, 117–122 (2008). https://doi.org/10.1016/j.molliq.2008.02.003

    Article  CAS  Google Scholar 

  8. Rock, Peter A.: MacMillan, 227 (1969)

  9. Saxena, I., Kumar, V., Devi, R.: Influence of tetra alkyl ammonium cation on thermo-physical properties of N,N-dimethyl formamide with 1,4-dioxane at different temperatures. Russ. J. Phys. Chem. B 12, 17–27 (2018). https://doi.org/10.1134/S1990793118010244

    Article  CAS  Google Scholar 

  10. Saxena, I., Kumar, V., Devi, R.: Influence of tetra alkyl ammonium cation and temperature on molecular interactions involves in binary liquid mixtures of dioxane and DMF at various temperatures. IOSR J. Appl. Chem. 10, 26–36 (2017). https://doi.org/10.9790/5736-1004012636

    Article  CAS  Google Scholar 

  11. Govinda, V., Vasantha, T., Khan, I., Venkatesu, P.: Effect of the alkyl chain length of the cation on the interactions between water and ammonium-based ionic liquids: experimental and COSMO-RS studies. Ind. Eng. Chem. 54(90), 13–9026 (2015). https://doi.org/10.1021/acs.iecr.5b01796

    Article  CAS  Google Scholar 

  12. Eyring, H., Kincaid, J.F.: Free volumes and Free angle ratios of molecules in liquids. J. Chem. Phys. 6, 620–629 (1938). https://doi.org/10.1063/1.1750134

    Article  ADS  Google Scholar 

  13. Saxena, I., Kumar, V.: Influence of tetraalkylammonium chain length cation on molecular interactions of dioxane-DMSO-H2O mixtures using ultrasonic technique at various temperatures. Ind. J. Chem. Sec. A 57A, 1454–1463 (2018)

    CAS  Google Scholar 

  14. Saxena, I., Kumar, V.: Ultrasonic speed and related acoustical and thermodynamic activation parameters of (2E, 6E)-bis (4-hydroxybenzylidene)-4-methylcyclohexanone in 1,4-dioxane, ethanol and tetrahydrofuran solutions at 298, 303, 308, and 313K. J. Pure Appl. Ultra. 41, 36–45 (2020)

    Google Scholar 

  15. Kumar, V.: The study of possible cause of weak and strong ionic interactions in binary electrolyte solution mixtures using ultrasonic and apparent molar volume measurements. Ph.D. Thesis, University of Lucknow, http://hdl.handle.net/10603/312197 (2019)

Download references

Acknowledgements

The author thanks the Head of the Department of Chemistry, Lucknow University, for providing the research facility in the Department.

Funding

This research received no specific grant from any funding agency in the public, commercial, or not-for-profit sectors.

Author information

Authors and Affiliations

  1. Department of Chemistry, University of Lucknow, Lucknow, U.P, 226007, India

    I. Saxena, V. Kumar & Aditya Gupta

Authors
  1. I. Saxena
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. V. Kumar
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Aditya Gupta
    View author publications

    You can also search for this author in PubMed Google Scholar

Contributions

Vijay Kumar involved in the data collection, interpretation, and review for vital intellectual content; Aditya Gupta helped in the manuscript preparation. Indu Saxena supervision granted final permission to the published version.

Corresponding author

Correspondence to I. Saxena.

Ethics declarations

Conflict of interest

We have no conflicts of interest to disclose. All authors declare that they have no conflicts of interest.

Additional information

Publisher's Note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Rights and permissions

Springer Nature or its licensor (e.g. a society or other partner) holds exclusive rights to this article under a publishing agreement with the author(s) or other rightsholder(s); author self-archiving of the accepted manuscript version of this article is solely governed by the terms of such publishing agreement and applicable law.

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Saxena, I., Kumar, V. & Gupta, A. An Overview of Molecular Interaction Studies of Binary/Ternary Liquid Mixtures with R4NI Salts Using Ultrasonic Velocity, Transport, Apparent Molar Volume, and Dielectric Constant Properties. J Solution Chem 53, 182–202 (2024). https://doi.org/10.1007/s10953-023-01251-w

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-023-01251-w

Keywords

Search

Navigation