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An Overview of Molecular Interaction Studies of Binary/Ternary Liquid Mixtures with R4NI Salts Using Ultrasonic Velocity, Transport, Apparent Molar Volume, and Dielectric Constant Properties

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Abstract

Due to the exceptional characteristics which result from using the ultrasonic technique, transport properties and related acoustical parameters of binary/ternary systems of different % compositions at variable temperatures with adding Et4NI to Pen4NI salts (0.14 mol·L−1) with increasing size of alkyl chain length cation, and investigated the inter-ionic interactions, molecular interactions, molecular rearrangement, molecular association, etc. Numerous theories and intermolecular interactions like dipole–dipole, dipole–induced dipole, solute–solvent, dispersive type, and H-bonding interaction between the components had shown that densities and transport properties provide a deep and meaningful insight into various interactions taking place between the liquid mixtures with salts. Such observations in the presence of specific molecular interactions of binary solutions and structural effects were analyzed based on measured and derived thermodynamical parameters.

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Acknowledgements

The author thanks the Head of the Department of Chemistry, Lucknow University, for providing the research facility in the Department.

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  1. Department of Chemistry, University of Lucknow, Lucknow, U.P, 226007, India

    I. Saxena, V. Kumar & Aditya Gupta

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  1. I. Saxena
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Vijay Kumar involved in the data collection, interpretation, and review for vital intellectual content; Aditya Gupta helped in the manuscript preparation. Indu Saxena supervision granted final permission to the published version.

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Saxena, I., Kumar, V. & Gupta, A. An Overview of Molecular Interaction Studies of Binary/Ternary Liquid Mixtures with R4NI Salts Using Ultrasonic Velocity, Transport, Apparent Molar Volume, and Dielectric Constant Properties. J Solution Chem 53, 182–202 (2024). https://doi.org/10.1007/s10953-023-01251-w

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