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Density and Viscosity of Polyethylene Glycol 400 + 1,2-Propanediamine Binary Mixtures at T = (293.15–318.15) K and Spectral Analysis

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Abstract

In this study, the density (ρ) and viscosity (η) of binary mixed solutions of PEG400 and 1,2-PDA at T = (293.15–318.15) K under atmospheric pressure were determined. With these data, the mixed solutions were investigated for excess properties, i.e., deviation viscosity (∆η), excess molar volume (\({\text{V}}_{m}^{\text{E}}\)), and excess Gibbs free energy (∆G*E). The deviations of Δη, \({\text{V}}_{m}^{\text{E}}\), and ∆G*E from ideal solution behavior are indicative of strong intermolecular interactions between PEG400 and 1,2-PDA. Through the study of the spectral properties of the mixture (FTIR, Raman, UV–Vis, FLS, and 1H.NMR), it is more clearly proved that the interaction between the molecules of the mixture is hydrogen bonding. The results provide a basis for engineering design, and fundamental data for the application of the binary system in a wider range of fields.

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Abbreviations

cal. and exp:

Calculated and experimental data

ρ :

Density, g·cm−3

v :

Kinematic viscosity, mm2·s  − 1

η :

Dynamic viscosity, mPa·s

\({\text{V}}_{m}^{\text{E}}\) :

Excess molar volume, cm3·mol−1

Δη :

Viscosity deviation, mPa·s

ΔG * E :

Free energy, kJ·mol−1

V φ,1 V φ, 2 :

Apparent molar volumes, cm3·mol−1

\({\overline{V} }_{1}\) and \({\stackrel{\mathrm{-}}{V}}_{2}\) :

Partial molar volumes, cm3·mol−1

α p :

Isobaric thermal expansion coefficients, K−1

R :

Ideal gas constant, 8.314 J·mol−1·K−1

A and B :

Viscometer constants

ΔS max :

Molar mixing entropy, kJ·mol−1

γ 1 and γ 2 :

Activity coefficient

AAD%:

Average deviation

x i :

Molar fraction

M i :

Relative molecular mass, g·mol−1

A i :

Polynomial coefficient

σ :

Standard deviation

V, \({V}_{\text{1}}^{\text{0}}\) and \({V}_{\text{2}}^{\text{0}}\) :

Molar volume, cm3·mol−1

r :

Molar volume ratio

ΔG * :

Activating Gibbs free energy, kJ·mol−1

h :

Planck’s constant

N A :

Avogadro’s constant

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Acknowledgements

This work was supported by the Program for Grassland Excellent Talents of Inner Mongolia Autonomous Region, the Inner Mongolia Science and Technology Key Projects, and Beijing Boyuan Hengsheng High-Tech. Co., Ltd., Beijing, China (HA2157).

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Authors and Affiliations

  1. Inner Mongolia Engineering Research Center for CO2 Capture and Utilization, Inner Mongolia University of Technology, Hohhot, 010051, China

    Gang Xing, Xuan Liu, Jialin Wu, Wenxue Wang, Zhaojun Wu & Jianbin Zhang

  2. Hebei Provincial Key Lab of Green Chemical Technology and High Efficient Energy Saving, School of Chemical Engineering and Technology, Hebei University of Technology, Tianjin, 300130, China

    Gang Xing, Xuan Liu, Jialin Wu, Wenxue Wang & Jianbin Zhang

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  1. Gang Xing
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Xing, G., Liu, X., Wu, J. et al. Density and Viscosity of Polyethylene Glycol 400 + 1,2-Propanediamine Binary Mixtures at T = (293.15–318.15) K and Spectral Analysis. J Solution Chem 52, 263–287 (2023). https://doi.org/10.1007/s10953-022-01228-1

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