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Volumetric and Acoustic Behavior of PEG-200 and PEG-600 in Aqueous D-Mannitol solutions at Different Temperatures

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Abstract

The interlinkage among the molecules of polyethylene glycols (PEG-200 and PEG-600) in aqueous D-Mannitol solutions are analyzed in the current investigation from the combination of acoustic and volumetric techniques. The densities and speeds of sound of the ternary mixtures of (water + d-mannitol + PEG-200/PEG-600) have been obtained at 293.15, 298.15, 303.15, 308.15 K as the function of D-mannitol concentration (0.01, 0.03 and 0.05) mol·kg−1 using an Anton Paar DSA 5000 M. From the experimental data, various apparent molar and partial molar properties are calculated along with the partial molar transfer properties. Further, the partial molar expansibilities with its first derivative are calculated including the pair-triplet coefficients using McMillan–Mayer theory from the calculated derived parameters. The result is represented in terms of (solute–solvent) interactions and prevailing interaction in mixtures. By the perusal of these parameters, the results have been rationalized in terms of the competing patterns of physicochemical interactions of solutes and the solvents.

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Authors and Affiliations

  1. Department of Physics, Lovely Professional University, Phagwara, Punjab, 144401, India

    Harsimaran Kaur, N. Chakraborty & K. C. Juglan

  2. Department of Chemistry, Dr. B R Ambedkar NIT, Jalandhar, Punjab, 144 011, India

    Harsh Kumar

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  1. Harsimaran Kaur
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Correspondence to K. C. Juglan.

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Kaur, H., Chakraborty, N., Juglan, K.C. et al. Volumetric and Acoustic Behavior of PEG-200 and PEG-600 in Aqueous D-Mannitol solutions at Different Temperatures. J Solution Chem 50, 1079–1102 (2021). https://doi.org/10.1007/s10953-021-01105-3

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