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Experimental Determination and Correlation of Liquid–Liquid Equilibria Data for the Ternary Systems of Water + 1-Butanol + Solvents (Isophorone and Mesityl Oxide) at Different Temperatures

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Abstract

Liquid–liquid equilibria (LLE) data for {water + 1-butanol + isophorone} and {water + 1-butanol + mesityl oxide} ternary systems were investigated systematically at different temperatures under atmospheric pressure. The Othmer–Tobias and Bachman equations were applied to analyze the dependability of the experimental LLE data. Selectivities and distribution coefficients were used to evaluate the extractive efficiency of the extractants. The Non-Random Two Liquid (NRTL) and Universal Quasi-Chemical (UNIQUAC) models were applied to correlate the studied systems and were well represented with all root mean square deviations (RMSD) less than 0.2%. Meanwhile, binary interaction parameters among these compounds were acquired during the correlation process.

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Authors and Affiliations

  1. State Key Laboratory of Heavy Oil Processing, College of Chemical Engineering, China University of Petroleum (East China), Qingdao, 266580, Shandong, People’s Republic of China

    Yingmin Yu, Lili Zhang, Chuanfu Zhu, Xin Huang, Zhaohui Liao & Qingsong Li

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  1. Yingmin Yu
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  2. Lili Zhang
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Yu, Y., Zhang, L., Zhu, C. et al. Experimental Determination and Correlation of Liquid–Liquid Equilibria Data for the Ternary Systems of Water + 1-Butanol + Solvents (Isophorone and Mesityl Oxide) at Different Temperatures. J Solution Chem 49, 1–15 (2020). https://doi.org/10.1007/s10953-019-00939-2

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