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Partial Molar Volumes and Isentropic Compressions of Cyclic Ethers in Aqueous Solutions from 288.15 to 313.15 K at Atmospheric Pressure

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Abstract

The partial molar volumes and isentropic compressions of aqueous solutions of tetrahydrofuran, tetrahydropyran, 1,4-dioxane, tetrahydropyran-2-methanol, 3-hydroxytetrahydrofuran, and tetrahydrofurfuryl alcohol were measured at 288.15, 298.15, and 313.15 K. Results are analyzed in terms of the effects of group addition to the molar volumes and isentropic compressions. The temperature dependence of the molar volumes and compressions, and their group contributions, are used to characterize changes in hydration.

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Acknowledgements

Luke Brown (’17) joined this project when he was a rising sophomore in the summer of 2014 and worked on it until the conclusion of his Senior Research Project. We would like to thank the Rollins College Collaborative Summer Research Program and the Rollins College Chemistry Department Hellwege Research fund for supporting Luke Brown.

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  1. Department of Chemistry, Rollins College, Winter Park, FL, 32789, USA

    Pedro Bernal & Luke Brown

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Correspondence to Pedro Bernal.

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Bernal, P., Brown, L. Partial Molar Volumes and Isentropic Compressions of Cyclic Ethers in Aqueous Solutions from 288.15 to 313.15 K at Atmospheric Pressure. J Solution Chem 47, 387–408 (2018). https://doi.org/10.1007/s10953-018-0725-0

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