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Liquid–Liquid Equilibrium of Ternary Systems of Methyl Isobutyl Ketone + o-Cresol + Water at 298.2, 313.2 and 323.2 K

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Abstract

Liquid–liquid equilibrium (LLE) data for the methyl isobutyl ketone + o-cresol + water ternary system have been experimentally measured from 298.2 to 323.2 K below 101 kPa. The measured LLE data were verified to be highly consistent through the Othmer–Tobias and Hand equations. The extraction efficiency of methyl isobutyl ketone for o-cresol was assessed by the distribution coefficient and separation factor. The experimental results correlated well with two excess Gibbs energy models: non-random two-liquid and universal quasi chemical, which also yielded binary interaction parameter.

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Acknowledgments

Financial support from the National Science Foundation of China (21506066), State Key Laboratory of Pulp and Paper Engineering (201708), the Guangzhou Technology Project (20181002SF0525), and the Fundamental Research Funds for the Central Universities SCUT (2017ZD069) are gratefully acknowledged.

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Authors and Affiliations

  1. Department of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, 510640, People’s Republic of China

    Yun Chen, Kangning Xiong, Shaoming Zhou, Huimin Wang & Libo Li

  2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou, 510640, People’s Republic of China

    Yun Chen, Kangning Xiong, Shaoming Zhou, Huimin Wang & Libo Li

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  1. Yun Chen
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  2. Kangning Xiong
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Correspondence to Yun Chen or Libo Li.

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Chen, Y., Xiong, K., Zhou, S. et al. Liquid–Liquid Equilibrium of Ternary Systems of Methyl Isobutyl Ketone + o-Cresol + Water at 298.2, 313.2 and 323.2 K. J Solution Chem 46, 2204–2213 (2017). https://doi.org/10.1007/s10953-017-0698-4

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