Polyvinylpyrrolidone Behavior in Water/Ethanol Mixed Solvents: Comparison of Modeling Predictions with Experimental Results
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The objective of this work is to study the behavior of a neutral polymer, polyvinylpyrrolidone (PVP), in a mixture of water and ethanol. A comparison of the experimental results with a theoretical model of effective solvent interaction with polymer (ESIP) was made. To do so, dynamic light scattering experiments were used to measure the hydrodynamic radius of PVP (M w = 3.6 × 105 g·mol−1) as a function of the ethanol fraction, x A, in the medium at 25 °C. We show that the polymer adopts an ideal chain–globule–coil conformation transition as the ethanol molar fraction varies. This transition is attributed to the change of the solvent quality which results from water and ethanol complex formation. On the other hand, the ternary PVP/water/ethanol system was described by the ESIP model. From the polymer–effective solvent interaction, the second virial coefficient of the polymer/effective solvent and the preferential adsorption parameter were calculated. The obtained results are in agreement with the reported experiments.
KeywordsPolymer Mixed solvents Dynamic light scattering Effective solvent Model
The authors gratefully acknowledge financial support from the Tunisian Ministry of Education, Research and Technology.
- 6.Guettari, M., Ajroudi, L., Tajouri, T., Bitar, A., Elaissari, H.: A temperature effect on the intrinsic viscosity of aqueous poly(N-vinylcaprolactam) solution. J. Colloid Sci. Biotechnol. 3, 351–354 (2014)Google Scholar
- 12.Mukherji, D., Marques, C.M., Kremer, K.: Polymer collapse in miscible good solvents is a generic phenomenon driven by preferential adsorption. Nat. Commun. 5(4882), 1–16 (2014)Google Scholar
- 14.Mark, J.E.: Polymer Data Handbook. Oxford University Press, New York (1999)Google Scholar
- 24.Yilmaz, H.: Excess properties of alcohol–water systems at 298.15 K. Turk. J. Phys. 26, 243–246 (2002)Google Scholar
- 28.Teraoka, I.: Polymer Solutions, Introduction to Physical Properties. Wiley-Interscience, New York (2002)Google Scholar
- 29.Barton, A.F.M.: Handbook of Solubility Parameters and Other Cohesion Parameters, 2nd edn. CRC Press, Boca Raton (1992)Google Scholar