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Density and Viscosity of a Ternary \( x_{1} \) 1-Hexene(1) + \( x_{2} \) 1-Octene(2) + (1 − x 1 − x 2) 1-Decene(3) Mixture at High Temperatures and High Pressures

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Abstract

The density and viscosity of a ternary 1-hexene(1) + 1-octene(2) +1-decene(3) mixture (\( w_{1} = w_{2} = w_{3} = 0.333 \) weight fractions or \( x_{1} = 0.4257 \),\( x_{2} = 0.3190 \), \( x_{3} = 0.2553 \) mole fractions of 1-hexene, 1-octene, and 1-decene, respectively) have been simultaneously measured over the temperature range from (298 to 471) K and at pressures up to 196 MPa using a combined method of hydrostatic weighing and falling-body techniques, respectively. The combined expanded uncertainties of the density, pressure, temperature, concentration, and viscosity measurements at the 95% confidence level with a coverage factor of k = 2 are estimated to be (0.15 to 0.30)%, 0.05%, 0.02 K, 0.005 mol%, and (1.5 to 2.0)%, respectively. The measured densities and viscosities were used to calculate the excess molar volumes and viscosity differences. The excess molar properties (\( G_{\text{m}}^{\text{E}} , \, H_{\text{m}}^{\text{E}} , \, S_{\text{m}}^{\text{E}} \) and \( C_{\text{pm}}^{\text{E}} \)) and their pressure derivatives as a function of temperature and pressure have been calculated using the derived excess molar volumes. The measured viscosities were used to develop a theoretically based viscosity correlation model (Arrhenius–Andrade type equation) for the mixture.

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Authors and Affiliations

  1. Kazan National Research Technological University, Kazan, Russian Federation

    Damir I. Sagdeev & Marina G. Fomina

  2. Dagestan State University, Makhachkala, Dagestan, Russian Federation

    Ilmutdin M. Abdulagatov

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  1. Damir I. Sagdeev
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  2. Marina G. Fomina
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  3. Ilmutdin M. Abdulagatov
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Correspondence to Ilmutdin M. Abdulagatov.

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Sagdeev, D.I., Fomina, M.G. & Abdulagatov, I.M. Density and Viscosity of a Ternary \( x_{1} \) 1-Hexene(1) + \( x_{2} \) 1-Octene(2) + (1 − x 1 − x 2) 1-Decene(3) Mixture at High Temperatures and High Pressures. J Solution Chem 46, 966–988 (2017). https://doi.org/10.1007/s10953-017-0617-8

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