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Chemical Equilibrium for the Reacting System Acetic Acid–Ethanol–Ethyl Acetate–Water at 303.15 K, 313.15 K and 323.15 K

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Abstract

The chemical equilibrium (CE) for the quaternary reacting system ethanol–acetic acid–ethyl acetate–water was studied at 303.15, 313.15 and 323.15 K and atmospheric pressure. The CE compositions were determined by gas chromatography and nuclear magnetic resonance analytical methods. The thermodynamic constants of CE at 303.15, 313.15 and 323.15 K were calculated based on the obtained experimental data with the use of the NRTL model.

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Acknowledgements

Maya Trofimova is grateful to Russian Foundation for Basic Research for the support of this study (RFBR project 16-33-00129). Maria Toikka is grateful for the scholarship of President of Russian Federation (SP-2140.2016.1). The authors acknowledge Resource Center of Saint Petersburg State University “Magnetic Resonance Research Center”. Authors are grateful to NIST ThermoData Engine group for the data on the properties of considered system.

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Authors and Affiliations

  1. Department of Chemical Thermodynamics and Kinetics, Saint Petersburg State University, Universitetskiy Prospect 26, Peterhof, St. Petersburg, Russia, 198504

    Alexandra Golikova, Artemiy Samarov, Maya Trofimova, Maria Toikka, Oleg Pervukhin & Alexander Toikka

  2. Laboratory of Biomolecular NMR, Saint Petersburg State University, St. Petersburg, Russia, 199034

    Sevastyan Rabdano

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  1. Alexandra Golikova
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  2. Artemiy Samarov
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  7. Alexander Toikka
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Correspondence to Maria Toikka.

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Golikova, A., Samarov, A., Trofimova, M. et al. Chemical Equilibrium for the Reacting System Acetic Acid–Ethanol–Ethyl Acetate–Water at 303.15 K, 313.15 K and 323.15 K. J Solution Chem 46, 374–387 (2017). https://doi.org/10.1007/s10953-017-0583-1

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