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Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol

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Abstract

The molar conductivities of silver nitrate and perchlorate solutions in aqueous ethanol (X EtOH = 0.5–0.9 and X EtOH = 0.9, respectively) were measured. Using the conductometry data, the values of dissociation constants and limiting conductivities (λ 0) of these electrolytes were calculated. The results were discussed by employing a solvation-thermodynamic approach. The hydrodynamic radii of Ag+, \( {\text{NO}}_{3}^{ - } \) and \( {\text{ClO}}_{4}^{ - } \) ions were estimated.

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Acknowledgments

Study was carried in the framework of State Task of the Ministry of Education and Science of the Russian Federation (Project 2293) and with financial support of Council on Grants of the President of the Russian Federation. Aleksandr Levantovskii, MSc, the developer of MagicPlot software used for article preparation is greatly acknowledged.

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Authors and Affiliations

  1. Ivanovo State University of Chemistry and Technology, Research Institute of Thermodynamics and Kinetics of Chemical Processes, Sheremetevsky Ave 7, Ivanovo, Russian Federation, 153000

    G. A. Gamov, M. N. Zavalishin, I. V. Novikov, S. V. Dushina & V. A. Sharnin

  2. Institute of Solution Chemistry, Russian Academy of Sciences, Ivanovo, Russian Federation

    V. A. Sharnin

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  1. G. A. Gamov
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  2. M. N. Zavalishin
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  3. I. V. Novikov
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Correspondence to G. A. Gamov.

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Gamov, G.A., Zavalishin, M.N., Novikov, I.V. et al. Association and Solvation of Silver Nitrate and Perchlorate in Aqueous Ethanol. J Solution Chem 45, 286–298 (2016). https://doi.org/10.1007/s10953-016-0436-3

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