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Synthesis, Characterization, Physical Properties, and CO2 Absorption Performance of Monoethanolamine Glycinate Ionic Liquid

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Abstract

A new amino acid-functionalized ionic liquid (IL), monoethanolamine glycinate ([MEA][GLY]), was synthesized and characterized. Its physical properties were measured, including density, viscosity, surface tension, conductivity, and refractive index. The solubility of CO2 in [MEA][GLY] was determined. The ability of [MEA][GLY] to absorb CO2 was evaluated. [MEA][GLY] with an active amino group exhibits representative physical properties of a functionalized IL. The solubility of CO2 in the IL is more than 0.5 mol CO2/mol IL at room temperature and atmospheric pressure. The [MEA][GLY] and aqueous [MEA][GLY] ILs are thus good absorbents of CO2. The CO2 partial pressure and [MEA][GLY] concentration have a significant impact on their absorption.

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Acknowledgments

This work was funded by the University Graduate Scientific Research and Innovation Project of Jiangsu Province (Grant No. KYLX-0857), Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), the Students Practice and Innovation Project of Jiangsu Province (Grant No. 201510300078), and the Students Practice and Innovation of NUIST (Grant No. 201410300128). The reviewers are greatly appreciated for their very valuable and helpful comments.

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Authors and Affiliations

  1. Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, Nanjing University of Information Science and Technology, Nanjing, 210044, China

    Jian-Gang Lu, Zhen-Yu Lu, Shuang Cao & Liu Gao

  2. Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Nanjing University of Information Science and Technology, Nanjing, 210044, China

    Xiang Gao, Jia-Ting Wang, Yin-Qin Tang & Yue Chen

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  1. Jian-Gang Lu
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Correspondence to Jian-Gang Lu.

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Lu, JG., Lu, ZY., Cao, S. et al. Synthesis, Characterization, Physical Properties, and CO2 Absorption Performance of Monoethanolamine Glycinate Ionic Liquid. J Solution Chem 44, 1997–2007 (2015). https://doi.org/10.1007/s10953-015-0392-3

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  • DOI: https://doi.org/10.1007/s10953-015-0392-3

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