Abstract
The present paper reports a study of binary mixtures of benzene and acetic acid over the entire range of composition at temperatures of 288, 298, 308 and 318 K. The measured values of static dielectric constant, density, and refractive index of the binary mixtures are further used to evaluate the excess dielectric constant, excess molar volume, excess refractive index, molar and excess molar refraction at these temperatures. The values of excess dielectric constant and excess refractive index are positive whereas the excess molar volume is negative over the entire range of mole fractions of acetic acid. The results are discussed in light of the intermolecular interactions occurring between the benzene and acetic acid molecules. The excess parameters were fitted with the Redlich–Kister equation and the resulting estimated Redlich–Kister coefficients (a j ) and standard deviations are reported.
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Riddick, J.A., Bunger, W.B., Sakano, T.K.: Organic Solvents. Physical Properties and Methods of Purification, 4th edn. Wiley, New York (1986)
Lide, D.R.: CRC Handbook of Chemistry and Physics, 82nd edn. CRC Press, Boca Raton (2001–2002)
Sengwa, R.J., Sankhla, S., Sharma, S.: Characterization of heterogeneous interaction behaviour in ternary mixtures by a dielectric analysis: equi-molar H-bonded binary polar mixtures in aqueous solutions. J. Solution Chem. 35, 1037–1055 (2006)
Sengwa, R.J., Sankhla, S.: Characterization of heterogeneous interaction in binary mixtures of ethylene glycol oligomer with water, ethyl alcohol and dioxane by dielectric analysis. J. Mol. Liq. 130, 119–131 (2007)
Sengwa, R.J., Sankhla, S.: Dielectric properties of binary and ternary mixtures of alcohols: analysis of H-bonded interaction in complex systems. J. Non-Cryst. Solids 353, 4570–4574 (2007)
Sengwa, R.J., Sankhla, S., Shinyashiki, N.: Dielectric parameters and hydrogen bond interaction study of binary alcohol mixtures. J. Solution Chem. 37, 137–153 (2008)
Sengwa, R.J., Khatri, V., Sankhla, S.: Static dielectric constant, excess dielectric properties, and Kirkwood correlation factor of water–amides and water–amines binary mixtures. Proc. Indian Nat. Sci. Acad 74, 67–72 (2008)
Sengwa, R.J., Khatri, V., Sankhla, S.: Dielectric properties and hydrogen bonding interaction behaviour in binary mixtures of glycerol with amides and amines. Fluid Phase Equil. 266, 54–58 (2008)
Pawar, V.P.: Dielectric relaxation of propan-1-ol with chlorobenzene, 1,2-dichloroethane, and dimethylchloride at 288, 298, 308, and 318 K using time-domain reflectometry technique. J. Chem. Eng. Data 51, 882–885 (2006)
Gagliardi, L.G., Castells, C.B., Ràfols, C., Rosés, M., Bosch, E.: Static dielectric constants of acetonitrile/water mixtures at different and Debye-Hückel A and åB parameters for activity coefficients. J. Chem. Eng. Data 52, 1103–1107 (2007)
Hsieh, C.-J., Chen, J.-M., Li, M.-H.: Dielectric constants of aqueous diisopropanolamine, diethanolamine, N-methyldiethanolamine, triethanolamine, and 2-amino-2-methyl-1-propanol solutions. J. Chem. Eng. Data 52, 619–623 (2007)
Greenberg, A., Breneman, C.M., Liebman, J.F.: The Amide Linkage: Structural Significance in Chemistry, Biochemistry and Material Science. Wiley, New York (2002)
Barthel, J., Gores, H.J.: Solution chemistry: a cutting edge in modern electrochemical technology. In: Mamantov, G., Popov, A.J. (eds.) Chemistry of Nonaqueous Solutions—Current Progress. VCH, New York (1994)
Smyth, C.P., Rogers, H.E.: The dielectric polarization of liquids. VIII. Acetic and butyric acids. J. Am. Chem. Soc. 52, 1824–1830 (1930)
Murthy, G.V.L.N., Seshadri, T.R.: Raman effect and hydrogen bonds. Part V: Mixture of acetic acid with ethers (Dioxan and Acetal). Proc. Indian Acad. Sci., A, 16(1), 50–53 (1942)
Campbell, A.N., Gieskes, J.M.T.M.: The dielectric behavior of the system: acetic acid–chloroform–water at 25 & #xB0;C. Can. J. Chem. 42, 1379–1387 (1964)
Tidar, A.L., Kamble, S.P., Patil, S.S., Sharma, B.R., Khirade, P.W., Mehrotra, S.C.: Novel method for static dielectric constant measurement of liquids. Sensor Transducer J 23, 52–59 (2010)
Kolling, K.O.W., O’Hara, K., Stevens, T.L.: Dielectric constant measurements on the binary solvents: acetic acid–acetic anhydride and acetic anhydride–nitromethane. Trans. Kansas Acad. Sci. 66, 435–442 (1963)
Granados, K., Gracia-Fadrique, J., Amigo, A., Bravo, R.: Refractive index, surface tension, and density of aqueous mixtures of carboxylic acids at 298.15 K. J. Chem. Eng. Data 51, 1356–1360 (2006)
McMillan, W., McDonald, H.: Analytical data for systems carbon tetrachloride–acetic acid–benzene and carbon tetrachloride–tetrachloroethylene. Ind. Eng. Chem. Anal. Ed. 15(2), 114–116 (1943)
Buep, A.H., Baron, M.: Dielectric properties of binary systems. Carbon tetrachloride with benzene, with toluene, and with p-xylene at 298.15 and 308.15 K. J. Phys. Chem. 92, 840–843 (1988)
Vura, U.S., Durmaz, F., Kocyigit, O., Kocyigit, H., Muradoglu, V., Akin, B.: Excess molar volumes, viscosities, refractive index, and Gibbs energy of activation of binary biodiesel + benzene, and biosiesel + toluene mixtures at 298.15 and 303.15 K. Russ. J. Phys. Chem. A 82, 2260–2268 (2008)
Timmerman, J.: Physico-Chemical Constants of Pure Organic Compounds. Elsevier, New York (1950)
Kumbharkhane, A.C., Puranik, S.M., Mehrotra, S.C.: Dielectric relaxation studies of aqueous N, N-dimethylformamide using a picoseconds time domain technique. J. Solution Chem. 22, 219–229 (1993)
Tabellout, M., Lanceleur, P., Emery, J.R., Hayward, D., Pethrick, R.A.: Dielectric, ultrasonic and carbon-13 nuclear magnetic resonance relaxation measurements of t-butyl alcohol–water mixtures. J. Chem. Soc., Faraday Trans. 86, 1493–1501 (1990)
El-Dossoki, F.I.: Refractive index and density measurements for selected binary protic–protic, aprotic–aprotic, and aprotic–protic systems at temperatures from 298.15 K to 308.15 K. J. Chinese Chem. Soc. 54, 1129–1137 (2007)
Gupta, M., Vibhu, I., Shukla, J.P.: Refractive index, molar refraction deviation and excess molar volume of binary mixtures of 1,4-dioxane with carboxylic acids. Phys. Chem. Liquids 48, 415–427 (2010)
Baraldi, P., Giorgini, M.G., Manzini, D., Marchetti, A., Tassi, L.: Density, refractive index, and related properties for 2-butanone + n-hexane binary mixtures at various temperatures. J. Solution Chem. 31, 873–893 (2002)
Swain, B.B., Ray, G.S.: Studies on dielectric properties of binary mixtures of butanols in nonpolar solvents—Linear correlation factor, excess molar polarization and excess free energy. Jpn. J. Appl. Phys. 25, 209–214 (1986)
Ray, S.K., Rath, J., Dwivedi, C.: Excess molar polarization in binary mixtures of polar liquids. Phys. Chem. Liq. 39, 221–231 (2001)
Liu, Y.G.: Daum, Peter H.: Relationship of refractive index to mass density and self- consistency of mixing rules for multicomponent mixtures like ambient aerosols. Aerosol. Science 39, 974–986 (2008)
Pacak, P.: Polarizability and molecular radius of dimethylsulphoxide and dimethylformamide from refractive index data. J. Solution Chem. 16, 71–77 (1987)
Lazarte, M., Marigliano, A.C.G., Solimo, H.N., Lazarte, M.: Excess molar volume, viscosity, and molar refraction deviations, and liquid–vapor equilibrium at 303.15 K for chloroform + acetonitrile binary mixture. An infrared study. J. Solution Chem. 33, 1549–1556 (2004)
Kumar, A.: Estimates of internal pressure and molar refraction of imidazolium based ionic liquids as a function of temperature. J. Solution Chem. 33, 203–214 (2008)
Bruggeman, D.A.G.: Berechnung verschiedener physikalischer Konstanten von heterogen Substanzen. Ann. Phys. (Leipzig) 24, 636–664 (1935)
Puranik, S.M., Kumbharkhane, A.C., Mehrotra, S.C.: The static permittivity of binary mixtures using an improved Bruggeman model. J. Mol. Liq. 59, 173–177 (1994)
Hafaiedh, N., Toumi, A., Bouanz, M.: Density and refractive index in binary mixtures of triethylamine–water in the temperature interval 283.15 K–291.35 K. Phys. Chem. Liquids: An. International Journal. 47, 399–411 (2009)
Sastry, N.V., George, A., Jain, N.J., Bahadur, P.: Densities, relative permittivities, excess volumes, and excess molar polarizations for alkyl ester (methyl propanoate, methyl butanoate, ethyl propanoate, and ethyl butanoate) + hydrocarbons (n-heptane, benzene, chlorobenzene, and 1,1,2,2-Tetrachloroethane) at 308.15 K and 318.15 K. J. Chem. Eng. Data 44, 456–464 (1999)
Fujj, Y., Yamada, H., Mizuta, M.: Self-association of acetic acid in some organic solvents. J. Phys. Chem. 92, 6768–6772 (1988)
Sengwa, R.J., Khatri, V., Sankhla, S.: Static dielectric constants and Kirkwood correlation factor of the binary mixtures of N-methylformamide with formamide, N,N-dimethylformamide and N,N-dimethylacetamide. J. Solution Chem. 38, 763–769 (2009)
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Kamble, S.P., Sudake, Y.S., Patil, S.S. et al. Solute–Solvent Interaction of Benzene with Acetic Acid at Different Temperatures. J Solution Chem 43, 1830–1843 (2014). https://doi.org/10.1007/s10953-014-0229-5
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DOI: https://doi.org/10.1007/s10953-014-0229-5