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NMR Study of the Stoichiometry and Stability of 30-Crown-10 Complexes with Ca2+, Sr2+, Ba2+ and Pb2+ Cations in Acetonitrile–Dimethylformamide Binary Mixtures

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Abstract

The complexation reaction of 30-crown-10 (30C10) with Ca2+, Sr2+, Pb2+ and Ba2+ ions in a various deuterated acetonitrile–dimethyformamide binary mixtures was studied using proton nuclear magnetic resonance spectroscopy. The complexes were found to have a 1:1 ratio and their stability is in the order of Ba2+ > Pb2+ > Sr2+ > Ca2+. It was observed that the donicity of the solvents as expressed by the Gutmann donor numbers and stability of the resulting complexes have an inverse relationship.

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References

  1. Pedersen, C.J.: Cyclic polyethers and their complexes with metal salts. J. Am. Chem. Soc. 89, 7017–7036 (1967)

    Article  CAS  Google Scholar 

  2. Rounaghi, G.H., Eshaghi, Z., Ghiamati, E.: Thermodynamic study of complex formation between 18-crown-6 and potassium ion in some binary non-aqueous solvents using a conductometric method. Talanta 44, 275–282 (1997)

    Article  CAS  Google Scholar 

  3. Rounaghi, G.H., Soorgi, M.H., Kazemi, M.S.: Effect of non-aqueous solvents on stoichiometry and selectivity of complexes formed between 4′-nitrobenzo-15-crown-5 with Fe3+, Y3+, Cd2+, Sn4+, Ce3+ and Au3+ metal cations. Russ. J. Inorg. Chem. 55, 355–360 (2010)

    Article  CAS  Google Scholar 

  4. Rahimi-Nasrabadi, M., Pourmohamadian, S., Pourmortazavi, S.M., Ahmadi, F., Ganjali, M.R., Moghimi, A.: NMR study of the stoichiometry and stability of complexation reaction between Mg2+, Ca2+, Sr2+ and Ba2+ ions and 60-crown-20 in binary acetonitrile solvent mixtures. J. Incl. Phenom. Macrocycl. Chem. 73, 263–267 (2012)

    Article  CAS  Google Scholar 

  5. Rounaghi, G.H., Mohajeri, M., Doaei, M., Ghaemi, A.: Solvent influence upon complex formation between benzo-15-crown-5 and Mg2+, Ca2+, and Sr2+ cations in some pure and binary mixed solvents using conductometric method. J. Incl. Phenom. Macrocycl. Chem. 67, 443–450 (2010)

    Article  CAS  Google Scholar 

  6. Buchanan, G.W., Rastegar, M.F.: Solid state 13C NMR of 30-crown-10 ether and 30-crown-10·4H2O. Solid State Nucl. Mag. 20, 137–143 (2001)

    Article  CAS  Google Scholar 

  7. Kozlowski, C.A., Kozlowska, J.: PNP-16-crown-6 derivatives as ion carriers for Zn(II), Cd(II) and Pb(II) transport across polymer inclusion membranes. J. Membr. Sci. 326, 215–221 (2009)

    Article  CAS  Google Scholar 

  8. Ganjali, M.R., Hosseini, M., Basiripour, F., Javanbakht, M., Hashemi, O.R., Faal Rastegar, M., Shamsipur, M., Buchanen, G.W.: Novel coated-graphite membrane sensor based on N, N′-dimethylcyanodiaza-18-crown-6 for the determination of ultra-trace amounts of lead. Anal. Chim. Acta 464, 181–186 (2002)

    Article  CAS  Google Scholar 

  9. Aghaie, M., Giahi, M., Aghaie, H., Arvand, M., Pournaghdy, M., Yavari, F.: New Fe(II) Ion-selective electrode based on N-phenylaza-15-crown-5 as neutral carrier in PVC matrix. Desalination 247, 346–354 (2009)

    Article  CAS  Google Scholar 

  10. Ganjali, M.R., Rahimi-Nasrabadi, M., Maddah, B., Moghimi, A., Faal-Rastegar, M., Borhany, Sh., Namazian, M.: Sub-micro level monitoring of beryllium ions with a novel beryllium sensor based on 2,6-diphenyl-4-benzo-9-crown-3-pyridine. Talanta 63, 899–906 (2004)

    Article  CAS  Google Scholar 

  11. Mohammad Zdeh Kakhki, R., Rounaghi, G.H.: Selective uranyl cation detection by polymeric ion selective electrode based on benzo-15-crown-5. Mater. Sci. Eng 31, 1637–1642 (2011)

    Article  Google Scholar 

  12. Shamsipur, M., Popov, A.: Multinuclear NMR study of dibenzo-30-crown-10 complexes with sodium, potassium, and cesium ions in nonaqueous solvents. J. Am. Chem. Soc. 101, 4051–4055 (1979)

    Article  CAS  Google Scholar 

  13. Amini, M.K., Shamsipur, M.: Complex formation of silver, thallium and alkali cations with dibenzo-30-crown-10 in some non-aqueous solutions. Inorg. Chim. Acta 183, 65–69 (1999)

    Article  Google Scholar 

  14. Gholivand, M.B., Rahimi-Nasrabadi, M., Ganjali, M.R., Salavati-Niasari, M.: Highly selective and sensitive copper membrane electrode based on a new synthesized Schiff base. Talanta 73, 553–560 (2007)

    Article  CAS  Google Scholar 

  15. Ganjali, M.R., Gholivand, M.B., Rahimi-Nasrabadi, M., Maddah, B., Salavati-Niasari, M., Ahmadi, F.: Synthesis of a new octadentates Schiff’s base and its application in construction of a highly selective and sensitive lanthanum(III) membrane sensor. Sens. Lett. 4, 356–363 (2006)

    Article  CAS  Google Scholar 

  16. Rahimi-Nasrabadi, M., Ganjali, M.R., Gholivand, M.B., Ahmadi, F., Norouzi, P., Salavati-Niasari, M.: A cyclic voltammetry investigation of the complex formation between Cu2+ and some Schiff bases in binary acetonitrile/dimethylformamide mixtures. J. Mol. Struct. 885, 76–81 (2008)

    Article  CAS  Google Scholar 

  17. Rahimi-Nasrabadi, M., Ahmadi, F., Pourmortazavi, S.M., Ganjali, M.R., Alizadeh, K.: Conductometric study of complex formations between some substituted pyrimidines and some metal ions in acetonitrile and the determination of thermodynamic parameters. J. Mol. Liq. 144, 97–101 (2009)

    Article  CAS  Google Scholar 

  18. Sahmsipur, M., Shafiee Dastjerdi, L., Alizadeh, N., Bijanzadeh, H.R.: Competitive cesium-133 NMR spectroscopic study of complexation of different metal ions with dibenzo-21-crown-7 in acetonitriledimethylsulfoxide and nitromethane–dimethylsulfoxide mixtures. Spectrochim. Acta Part A 69, 1265–1270 (2008)

    Article  Google Scholar 

  19. Alizadeh, N., Haddadi, H.: Solvent isotope effects on the complexation and exchange kinetics of Tl(I), K+ and Na+ with 18-crown-6 by competitive NMR spectroscopy: competition between homo- and heterobimolecular cations exchange. Polyhedron 30, 1267–1273 (2011)

    Article  CAS  Google Scholar 

  20. Irandoust, M., Joshaghani, M., Rafiee, E., Pourshahbaz, M.: 31P NMR study of the stoichiometry, stability and thermodynamics of complex formation between palladium(II) acetate and bis(diphenylphosphino)ferrocene. Spectrochim. Acta Part A 74, 855–859 (2009)

    Article  Google Scholar 

  21. Shamsipur, M., Irandoust, M.: 7Li-NMR study of the stoichiometry, stability and exchange kinetics of Li+ ion with 12-crown-4, 15-crown-5 and cryptands C222, C221 and C211 in 50 % ionic liquid–acetonitrile mixtures. Polyhedron 31, 395–401 (2012)

    Article  CAS  Google Scholar 

  22. Irandoust, M., Daraei, H., Joshaghani, M., Gholivand, K., Gholivand, M.B.: 31P NMR study of the stoichiometry, stability and thermodynamics of new complexation between uranyl(II) nitrate and N-methyliminobis(methylenephosphonic acid) in two binary D2O–DMSO-d6 solvent mixtures. Polyhedron 30, 228–232 (2011)

    Article  CAS  Google Scholar 

  23. Gutmann, V.: The Donor-Acceptor Approach to Molecular Interactions. Plenum, New York (1978)

    Book  Google Scholar 

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Authors and Affiliations

  1. Department of Chemistry, Imam Hossein University, Tehran, Iran

    Mehdi Rahimi-Nasrabadi, Bozorgmehr Maddah & Abolghasem Moghimi

  2. Department of Chemistry, Razi University, Kermanshah, Iran

    Mojtaba Shamsipur

Authors
  1. Mehdi Rahimi-Nasrabadi
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  2. Bozorgmehr Maddah
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  3. Mojtaba Shamsipur
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  4. Abolghasem Moghimi
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Correspondence to Mehdi Rahimi-Nasrabadi.

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Rahimi-Nasrabadi, M., Maddah, B., Shamsipur, M. et al. NMR Study of the Stoichiometry and Stability of 30-Crown-10 Complexes with Ca2+, Sr2+, Ba2+ and Pb2+ Cations in Acetonitrile–Dimethylformamide Binary Mixtures. J Solution Chem 43, 623–631 (2014). https://doi.org/10.1007/s10953-014-0144-9

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  • DOI: https://doi.org/10.1007/s10953-014-0144-9

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