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1:1 and 1:2 Inclusion Complexes of Di-tert-butyl l-tartrate with α-Cyclodextrin: A Diffusion Study

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Abstract

The diffusion properties at two overall compositions of a ternary aqueous system containing α-cyclodextrin and a double-functional guest molecule, namely di-tert-butyl l-tartrate, have been studied by means of the Gouy interferometry. The experimental data are interpreted in terms of two independent chemical equilibria involving inclusion compounds. The elements of the diffusion coefficient matrix have been expressed as functions of the two equilibrium constants as well as of the diffusivities of the actual species occurring in solution. The reliability of the diffusion coefficients obtained through the Fujita–Gosting–Revzin procedure is also discussed in terms of its dependence on the composition of solutions used in the Gouy experiments.

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Acknowledgments

One of us (R.S.) had the opportunity to collaborate with Donald Miller for a long period since the mid 1980s while the other one (G.M.) had the chance to meet him during his last stays in Naples after 2000. Even with different experiences and memories, both of us had the possibility to appreciate Don’s human side, his communication skills, and his high scientific personality. This little contribution is in his memory and honor.

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  1. G.S.A. Service, Via Edoardo Nicolardi 21, 80131, Naples, NA, Italy

    Gaetano Mangiapia

  2. Dipartimento di Scienze Chimiche Complesso Universitario di Monte S. Angelo, Università degli Studi di Napoli “Federico II”, Via Cinthia, 80126, Naples, NA, Italy

    Roberto Sartorio

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  1. Gaetano Mangiapia
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  2. Roberto Sartorio
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Mangiapia, G., Sartorio, R. 1:1 and 1:2 Inclusion Complexes of Di-tert-butyl l-tartrate with α-Cyclodextrin: A Diffusion Study. J Solution Chem 43, 186–205 (2014). https://doi.org/10.1007/s10953-013-0124-5

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