Skip to main content
SpringerLink
Log in

Densities and Viscosities for Binary and Ternary Mixtures of 2-Methylbutan-2-ol (1) + Trichloroethylene (2) + Acetonitrile (3) at 298.15 K and at Ambient Pressure (81.5 kPa)

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

Densities (ρ) and viscosities (η) of ternary mixtures of 2-methylbutan-2-ol (1) + trichloroethylene (2) + acetonitrile (3) and the related binary mixtures of {2-methylbutan-2-ol (1) + trichloroethylene (2)}, {2-methylbutan-2-ol (1) + acetonitrile (3)}, and {trichloroethylene (2) + acetonitrile (3)} have been measured over the whole composition range at 298.15 K and at ambient pressure (81.5 kPa). Excess molar volumes \( V_{\text{m}}^{\text{E}} \), viscosity deviations Δη, and excess Gibbs energies of activation ΔG *E were derived from the experimental data. The binary and ternary data of \( V_{\text{m}}^{\text{E}} \), Δη, and ΔG *E for the binary and ternary mixtures were correlated as functions of the mole fraction by using the Redlich–Kister and the Cibulka equations. Kinematic viscosities of the binary mixtures were correlated by means of several semi-empirical equations to determine the fitting parameters and the SDs. The experimental results are analyzed to discuss the nature and strength of intermolecular interactions in these mixtures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Battino, R.: Volumes change on mixing for binary mixtures of liquids. Chem. Rev. 71, 5–45 (1971)

    Article  CAS  Google Scholar 

  2. Lundstrom, R., Goodwin, R.H.A., Frels, M.H.K., Caudwell, R.D., Trusler, M.P.J., Marsh, K.N.: Measurement of the viscosity and density of two reference fluids, with nominal viscosities at T = 298 K and p = 0.1 MPa of (16 and 29) mPa·s, at temperatures between (298 and 393) K and pressures below 55 MPa. J. Chem. Eng. Data 50, 1377–1388 (2005)

    Article  Google Scholar 

  3. Prigogine, I., Astarita, G.: The Molecular Theory of Solutions. North Holland, Amsterdam (1957)

    Google Scholar 

  4. Savage, J.A., Bisio, D.W.: Gas Treating with Chemical Solvents. Wiley, New York (1983)

    Google Scholar 

  5. Iloukhani, H., Khanlarzadeh, K.: Volumetric properties for binary and ternary systems consist of 1-chlorobutane, n-butylamine and isobutanol at 298.15 K and ambient pressure with application of the Prigogine–Flory–Patterson theory (PFP) and ERAS-model. Thermochim. Acta 502, 77–84 (2010)

    Article  CAS  Google Scholar 

  6. Iloukhani, H., Khanlarzadeh, K.: Densities, viscosities, and refractive indices for binary and ternary mixtures of N,N-dimethylacetamide (1) + 2-methylbutan-2-ol (2) + ethyl acetate (3) at 298.15 K for the liquid region and at ambient pressure. J. Chem. Eng. Data 51, 1226–1231 (2006)

    Article  CAS  Google Scholar 

  7. Fattahi, M., Iloukhani, H.: Excess molar volume, viscosity, and refractive index study for the ternary mixture 2-methyl-2-butanol (1) + tetrahydrofuran (2) + propylamine (3) at different temperatures. Application of the ERAS-model and Peng–Robinson–Stryjek–Vera equation of state. J. Chem. Thermodyn. 42, 1335–1345 (2010)

    Article  CAS  Google Scholar 

  8. Iloukhani, H., Almasi, M.: Densities, viscosities, excess molar volumes, and refractive indices of acetonitrile and 2-alkanols binary mixtures at different temperatures, Experimental results and application of the Prigogine–Flory–Patterson theory. Thermochim. Acta 495, 139–148 (2009)

    Article  CAS  Google Scholar 

  9. Redlich, O.J., Kister, A.T.: Thermodynamics of non electrolyte solutions, algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)

    Article  Google Scholar 

  10. Cibulka, I.: Estimation of the excess volume and density of nonelectrolytes from binary data. Collect. Czech. Commun. 47, 1414–1419 (1982)

    Article  CAS  Google Scholar 

  11. Grunberg, L., Nissan, A.H.: The energies of vaporisation, viscosity and cohesion and the structure of liquids. Trans. Faraday Soc. 45, 125–129 (1949)

    Article  CAS  Google Scholar 

  12. Hind, R.K., McLaughlin, E., Ubbelohde, A.R.: Structure and viscosity of liquids. Viscosity–temperature relationships of pyrrole and pyrrolidine. Trans. Faraday Soc. 56, 331–337 (1960)

    Article  CAS  Google Scholar 

  13. McAllister, A.R.: The viscosity of liquid mixtures. AI. Chem. J. 6, 427–433 (1960)

    CAS  Google Scholar 

  14. Frenkel, Y.I.: Kinematic Theory of Liquids. Oxford University Press, London (1946)

    Google Scholar 

  15. Kendall, J., Monroe, K.P.: Viscosity of liquids: theory, estimation, experiment, and data. J. Am. Chem. Soc. 39, 1787–1802 (1917)

    Article  CAS  Google Scholar 

  16. Riddick, J.A., Bunger, W.B., Sakano, T.A.: Organic Solvents. Wiley, New York (1986)

    Google Scholar 

  17. Dumitresco, V., Pantea, O.: Viscosities of binary mixtures of toluene with butan-1-ol and 2-methylpropan-2-ol. J. Serb. Chem. Soc. 70, 1313–1323 (2005)

    Article  Google Scholar 

Download references

Acknowledgments

The authors would like to thank the Bu-Ali Sina University for providing the necessary facilities to carry out the research.

Author information

Authors and Affiliations

  1. Department of Physical Chemistry, Faculty of Chemistry, Bu-Ali Sina University, Hamedan, Iran

    Hossein Iloukhani, Masoomeh Giahshenas & Kh. Khanlarzadeh

Authors
  1. Hossein Iloukhani
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Masoomeh Giahshenas
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kh. Khanlarzadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Hossein Iloukhani.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Iloukhani, H., Giahshenas, M. & Khanlarzadeh, K. Densities and Viscosities for Binary and Ternary Mixtures of 2-Methylbutan-2-ol (1) + Trichloroethylene (2) + Acetonitrile (3) at 298.15 K and at Ambient Pressure (81.5 kPa). J Solution Chem 42, 1949–1959 (2013). https://doi.org/10.1007/s10953-013-0090-y

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-013-0090-y

Keywords

Search

Navigation