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Volumetric and Acoustic Studies of Binary Liquid Mixtures of Dipropylene Glycol Dimethyl Ether with Methyl Acetate, Ethyl Acetate and n-Butyl Acetate in the Temperature Range T = (288.15, 293.15, 298.15, 303.15, and 308.15) K

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Abstract

Densities and ultrasonic speeds have been measured over the whole composition range for binary liquid mixtures of dipropylene glycol dimethyl ether, CH3(OC3H6)2OCH3, with methyl acetate, ethyl acetate, and n-butyl acetate using an Anton Paar DSA 5000 M density and speed sound analyzer at T = (288.15, 293.15, 298.15, 303.15, and 308.15) K and atmospheric pressure in order to evaluate the behavior of these binaries. From these data excess the molar volume, \( V_{m}^{\text{E}} \), and deviation in isentropic compressibility, ∆κ S , have been calculated. These excess properties have been fitted with the Redlich–Kister type polynomial equation to get their coefficients and standard deviations which provide a base for discussing the forces operating in solutions.

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  1. Department of Chemistry, Kurukshetra University, Kurukshetra, 136119, Haryana, India

    Amalendu Pal

  2. Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar, 144011, Punjab, India

    Harsh Kumar

  3. Department of Chemistry, M M University, Mullana, Ambala, Haryana, India

    Ritu Maan & Harish Kumar Sharma

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Pal, A., Kumar, H., Maan, R. et al. Volumetric and Acoustic Studies of Binary Liquid Mixtures of Dipropylene Glycol Dimethyl Ether with Methyl Acetate, Ethyl Acetate and n-Butyl Acetate in the Temperature Range T = (288.15, 293.15, 298.15, 303.15, and 308.15) K. J Solution Chem 42, 1988–2011 (2013). https://doi.org/10.1007/s10953-013-0086-7

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