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Volumetric Properties of 1,3-Dioxolane + Toluene + o- or p-Xylene Ternary Mixtures at 25.00 °C and Atmospheric Pressure

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Abstract

Excess molar volumes, \( V_{123}^{\text{E}} \), of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been determined dilatometrically over the entire composition range at 298.15 K. For thermodynamic consistency the experimental values were fitted to Redlich–Kister Equation. The \( V_{123}^{\text{E}} \) values of 1, 3-dioxolane (1) + toluene (2) + o- or p-xylene (3) ternary mixtures have been found to be negative over the whole composition range. It has been observed that \( V_{123}^{\text{E}} \) values calculated by graph theory are of the same sign and magnitude with respect to their experimental values.

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Acknowledgments

This study was supported by the Ministry of Education (MOE) of Korea through its BK21 Program and GAS plant R&D Centre funded by the Ministry of Land, Transportation and Maritime Affairs (MLTM) of the Korean Government.

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Authors and Affiliations

  1. Department of Chemical and Biomolecular Engineering, Yonsei University, 50 Yonsei-ro, Seodaemun-gu, Seoul, 120-749, Republic of Korea

    Satish Kumar & Il Moon

  2. Department of Chemistry, Maharshi Dayanand University, Rohtak, 124001, India

    V. K. Sharma

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  1. Satish Kumar
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  2. V. K. Sharma
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  3. Il Moon
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Correspondence to Satish Kumar.

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Kumar, S., Sharma, V.K. & Moon, I. Volumetric Properties of 1,3-Dioxolane + Toluene + o- or p-Xylene Ternary Mixtures at 25.00 °C and Atmospheric Pressure. J Solution Chem 42, 936–944 (2013). https://doi.org/10.1007/s10953-013-0017-7

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