Advertisement

Journal of Solution Chemistry

, Volume 41, Issue 11, pp 1937–1947 | Cite as

Oxidation Studies of Mn(III)–Amino Acid Chelating Agents

  • Ganesan Sivakumar
  • Nachimuthu KrishnaveniEmail author
  • Manickam UmayavalliEmail author
Article

Abstract

The kinetics of oxidation of ethylenediaminetetraacetic acid (Red) and nitrilotriacetic acid (Red) by trisacetatomanganese(III) dihydrate in dilute sulfuric acid and dilute perchloric acid media in nitrogen atmosphere were studied, where Red denotes the reductant in these reactions. At constant [Red], [H+], ionic strength and temperature, a first order dependence with respect to [Mn(III)] was observed. The rate increased with [Red] but was independent at higher [Red]. The rate was unaltered by the changes in [H+], ionic strength and added Mn(II). A suitable mechanism has been proposed to explain the observed kinetic data.

Keywords

Mn(III)–amino acid chelating agent complexes Ethylenediaminetetraacetic acid Nitrilotriacetic acid Trisacetatomanganese(III) dihydrate 

References

  1. 1.
    Jiang, Jh, Kucernak, A.: Electronically conducting polymer of manganese halide complex bearing 2,6-bis(imino)pyridyl ligands. Synth. Met. 128, 221–227 (2002)CrossRefGoogle Scholar
  2. 2.
    Sadlick, J.: Thermal initiation of vinyl polymerization by ceric solution. J. Polym. Sci. 19, 73–75 (1956)CrossRefGoogle Scholar
  3. 3.
    Ananthanarayanan, V.S., Santappa, M.: Kinetics of vinyl polymerization initiated by ceric ion in aqueous solution. J. Appl. Polym. Sci. 9, 2437–2449 (1965)CrossRefGoogle Scholar
  4. 4.
    Pramanick, D., Sarkar, S.K.: Mode of initiation in ceric salt initiated aqueous polymerization of methylmethacrylate. Colloid Polym. Sci. 254, 989–993 (1976)CrossRefGoogle Scholar
  5. 5.
    Drumond, A.Y., Waters, W.A.: Stages in oxidation of organic compounds by potassium permanganate. Part III. A kinetic study of the oxidation by manganic pyrophosphate. J. Chem. Soc., 3119–3123 (1953)Google Scholar
  6. 6.
    Senapathy, M., Samal, N.C., Mishra, R., Tripatty, B., Rout, S., Rout, M.K.: Polymerization of acrylonitrile iniated by a manganese(III) acetate glycerol redox system. J. Polym. Sci Polym. Chem. Ed. 21, 407–413 (1983)CrossRefGoogle Scholar
  7. 7.
    Drumond, A.Y., Waters, W.A.: Stages in oxidation of organic compounds by potassium permanganate. Part VI. Oxidation of ketones and pyruvic acid. J. Chem. Soc. 497–504 (1955)Google Scholar
  8. 8.
    Ganga Devi, N., Mahadevan, V.: Polymerization of acrylamide by the redox system pinacol–Mn(III). J. Polym. Sci. Polym. Lett. 10, 903–910 (1972)CrossRefGoogle Scholar
  9. 9.
    Kemp, J.J., Waters, W.A.: The oxidation of malonic acid by manganic sulphate. J. Chem. Soc. 4, 1489–1493 (1964)CrossRefGoogle Scholar
  10. 10.
    Drumond, A.Y., Waters, W.A.: Stages in oxidation of organic compounds by potassium permanganate. Part IV. Oxidation of malonic acid and its analogues. J. Chem. Soc. 2456–2467 (1954)Google Scholar
  11. 11.
    Ganga Devi, N., Mahadevan, V.: Redox polymerization. Kinetics of the reaction initiated by the malonic acid/Mn(III) system. Macromol. Chem. 152, 77–184 (1972)Google Scholar
  12. 12.
    Levesely, P., Waters, W.A.: Stages in oxidation of organic compounds by potassium permanganate. Part V. Oxidation of some α-hydroxy-acids by manganic pyrophosphate. J. Chem. Soc., 217–221 (1955)Google Scholar
  13. 13.
    Jose, T.P., Nandibewoor, S.T., Tuwar, S.M.: Kinetics and mechanism of the oxidation of vanillin by hexacyanoferrate(III) in aqueous alkaline medium. J. Solut. Chem. 35, 51–62 (2006)CrossRefGoogle Scholar
  14. 14.
    Sen Gupta, K.K., Das, S., Sen Gupta, S.: Kinetics and mechanism of the oxidation of thiosulphate by hexachloroplatinate(IV). Transition Met. Chem. 13, 155–159 (1988)CrossRefGoogle Scholar
  15. 15.
    Saha, S.K., Chaudruri, A.K.: Effect of amines on the ceric ion-initiated polymerization of vinyl monomer. II. Polymerization of acrylonitrile by ceric ion in presence of various substituted amines. J. Polym. Sci. Part A Polym. Chem. 10, 797–808 (1972)CrossRefGoogle Scholar
  16. 16.
    Hsu, W.C., Kuo, J.F., Chen, C.Y.: Aqueous polymerization of acrylamide initiated by cerium(IV)–amino acid chelating agent redox initiators. J. Polym. Sci. Part A Polym. Chem. 31, 267–270 (1993)CrossRefGoogle Scholar
  17. 17.
    Hsu, W.-C., Kuo, J.-F., Chen, C.-Y.: Aqueous polymerization of acrylamide initiated by cerium(IV)–ethylenediamine tetraacetic acid redox system. J. Polym. Sci. Part A Polym. Chem. 30, 2459–2466 (1992)CrossRefGoogle Scholar
  18. 18.
    Demappa, M.T.: Polymerization kinetics of methylmethacrylate by oxidation: reduction system using cerium(IV)/lactic acid in aqueous medium. J. Appl. Polym. Sci. 103, 3498–3505 (2006)CrossRefGoogle Scholar
  19. 19.
    Christianson, O.T., Anorg, Z.: Untersuchunger uber Managanverbindungen II. Manganiacetat und Alaune des Mangans. Allgem. Chem. 27, 315–340 (1901)Google Scholar
  20. 20.
    Andrulis, P.J., Dewar, M.J.S., Dietz, R., Hunt, J.R.: Aromatic oxidation by electron transfer. I. Oxidation of p-methoxytoluene. J. Am. Chem. Soc. 88, 5473–5478 (1966)CrossRefGoogle Scholar
  21. 21.
    Haragopal, M., Mahadevan, V.: Redox polymerization. 4. Kinetics of the polymerization of acrylic acid derivatives initiated by the system cyanoacetic acid/Mn(OCOCH3) in dimethylformamide. Macromol. Chem. 181, 1189–1198 (1980)CrossRefGoogle Scholar
  22. 22.
    Jeyakrishnan, A., Haragopal, M., Mahadevan, V.: Redox polymerization-kinetics of the reaction initiated by the CH2(CH)2–Mn(III) in aqueous H2SO4 and the systemCH2(CN)2–Mn(OAC)3 in DMF and acetic acid. J. Polym. Sci. Polym. Chem. Ed. 19, 1311–1318 (1981)CrossRefGoogle Scholar
  23. 23.
    Ratnasabapathy, S.: Some aspects of polymerization (kinetics of polymerization of N,N’-methylenebisacrylamide by redox systems involving Mn(III)). Ph.D. thesis, Madurai Kamaraj University (1989)Google Scholar
  24. 24.
    Vogel, A.I.: A textbook of quantitative inorganic analysis, p. 282. ELBS-Longmans Green and Co, London (1962)Google Scholar
  25. 25.
    Lineweaver, H., Burk, D.: The determination of enzyme dissociation constants. 5. J. Am. Chem. Soc. 56, 658–666 (1934)CrossRefGoogle Scholar
  26. 26.
    Nagarajan, A., Srinivasan, K.S.V.: Efficiency of ceric ions for oxidation and polymerization: A review. J. Macromol Sci. Pure Appl. Chem. 38, 53–76 (1998)CrossRefGoogle Scholar
  27. 27.
    Mottola, H.A.: Nitrilotriacetic acid as a chelating agent: applications, toxicology, and bio-environmental impact. Toxicol. Environ. Chem. 2, 99–161 (1974)CrossRefGoogle Scholar
  28. 28.
    Martell, A.E., Galvin, M.: Chemistry of the metal chelate compounds, 3rd edn, p. 21. Prentice Hall, Englewood Cliffs (1956)Google Scholar
  29. 29.
    Gangadevi, N., Mahadevan, V.: Redox polymerization, 5. Kinetics of the polymerization of acrylonitrile and methyl methacrylate initiated by the system cyanoacetic acid–Mn(III)(acac)3 in DMF and DMSO. Macromol. Chem. 182, 23–28 (1981)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2012

Authors and Affiliations

  1. 1.Department of ChemistryVelalar College of Engineering and TechnologyErodeIndia
  2. 2.PG and Research Department of ChemistryArulmigu Palani Andavar College of Arts and CulturePalaniIndia

Personalised recommendations