Abstract
Densities, ρ, and viscosities, η, of binary mixtures of 2-methyl-2-propanol with acetone (AC), ethyl methyl ketone (EMK) and acetophenone (AP), including those of the pure liquids, were measured over the entire composition range at 298.15, 303.15 and 308.15 K. From these experimental data, the excess molar volume \(V_{\mathrm{m}}^{\mathrm{E}}\), deviation in viscosity Δη, partial and apparent molar volumes (\(\overline{V}_{\mathrm{m},1}^{\,\circ }\), \(\overline{V}_{\mathrm{m},2}^{\,\circ }\), \(\overline{V}_{\phi ,1}^{\,\circ}\) and \(\overline{V}_{\phi,2}^{\,\circ} \)), and their excess values (\(\overline{V}_{\mathrm{m},1}^{\,\circ \mathrm{E}}\), \(\overline{V}_{\mathrm{m,2}}^{\,\circ \mathrm{ E}}\), \(\overline {V}_{\phi \mathrm{,1}}^{\,\circ \mathrm{ E}}\) and \(\overline{V}_{\phi \mathrm{,2}}^{\,\circ \mathrm{ E}}\)) of the components at infinite dilution were calculated. The interaction between the component molecules follows the order of AP > AC > EMK.
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Rajagopal, K., Chenthilnath, S. & Nain, A.K. Volumetric and Viscometric Studies in Binary Liquid Mixtures of 2-Methyl-2-propanol with Some Ketones at Different Temperatures. J Solution Chem 41, 1401–1411 (2012). https://doi.org/10.1007/s10953-012-9870-z
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DOI: https://doi.org/10.1007/s10953-012-9870-z