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Densities and Excess Molar Volumes of Alkane (Heptane, Octane, Nonane, or Decane) + Thiophene from T=293.15 to 313.15 K

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Abstract

Densities of four binary systems composed of an alkane (heptane, octane, nonane, or decane) and thiophene were measured at temperatures from 293.15 to 313.15 K at atmospheric pressure (0.7 atm). Measurements were made covering the full range of compositions for all systems studied and for the pure compounds by using a vibrating-tube densimeter (VTD). Excess molar volumes have been obtained from these experimental results and were fitted to a Redlich–Kister type expansion. The excess molar volumes exhibit positive deviations from ideal behavior for all of the binary systems studied here.

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Acknowledgements

We are grateful to Instituto Politécnico Nacional (IPN), and Consejo Nacional de Ciencia y Tecnología (CONACYT) of México for their financial support under grant projects: SIP20111066 and 80543, respectively. We also want to thank Dr. José Gonzalo Hernández Cortez for his help on GC analyses, and M.C. Sergio Alvarez Badillo for his assistance on literature data review of pure compounds.

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Authors and Affiliations

  1. Laboratorio de Investigación en Fisicoquímica y Materiales, Departamento de Ingeniería Química Industrial, Escuela Superior de Ingeniería Química e Industrias Extractivas, Instituto Politécnico Nacional, Edif. Z5, 2° piso, UPALM, Col. Zacatenco, Mexico D.F., Mexico

    Edgar Cisneros-Pérez, Carmen M. Reza-San Germán, María E. Manríquez-Ramírez & Abel Zúñiga-Moreno

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  1. Edgar Cisneros-Pérez
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  2. Carmen M. Reza-San Germán
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  3. María E. Manríquez-Ramírez
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  4. Abel Zúñiga-Moreno
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Corresponding author

Correspondence to Abel Zúñiga-Moreno.

Glossary of Symbols Used in the Tables

Glossary of Symbols Used in the Tables

ρ (g⋅cm−3):

densities

V E (cm3⋅mol−1):

excess molar volumes

A i :

parameters of Redlich–Kister expansion (Eq. 4)

σ :

standard deviation

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Cisneros-Pérez, E., Reza-San Germán, C.M., Manríquez-Ramírez, M.E. et al. Densities and Excess Molar Volumes of Alkane (Heptane, Octane, Nonane, or Decane) + Thiophene from T=293.15 to 313.15 K. J Solution Chem 41, 1054–1066 (2012). https://doi.org/10.1007/s10953-012-9851-2

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  • DOI: https://doi.org/10.1007/s10953-012-9851-2

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