Skip to main content
SpringerLink
Log in

Apparent Molar Volumes of Some Sodium Sulfonamides in Water at Several Molalities and Temperatures

  • Published:
Journal of Solution Chemistry Aims and scope Submit manuscript

Abstract

In this article, measured densities of aqueous solutions of sodium sulfadiazine, sodium sulfamerazine and sodium sulfamethazine are reported as a function of molality from 0.0500 to 0.5000 mol⋅kg−1 and as a function of temperature at (278.15, 283.15, 288.15, 293.15, 298.15, 303.15, 308.15 and 313.15) K. The apparent molar volumes, partial molar volumes at infinite dilution and partial molar expansibilities were calculated. The dependence of these properties upon temperature is shown. The results are interpreted in terms of solute-solvent interactions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Subscribe and save

Springer+ Basic
$34.99 /Month
  • Get 10 units per month
  • Download Article/Chapter or eBook
  • 1 Unit = 1 Article or 1 Chapter
  • Cancel anytime
Subscribe now

Buy Now

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. Gelone, S., O’Donell, J.A.: In: Gennaro A.R. (ed.) Remington: The Science and Practice of Pharmacy, 21st edn., pp. 1630–1633. Williams & Wilkins, Baltimore (2005),

    Google Scholar 

  2. Labastidas, I., Martínez, F.: Aspectos termodinámicos de la solubilidad acuosa de algunas sales orgánicas de interés farmacéutico. Acta Farm. Bonaerense 25, 55–63 (2006)

    CAS  Google Scholar 

  3. Martínez, F., Gómez, A.: Thermodynamic study of the solubility of some sulfonamides in octanol, water, and the mutually saturated solvents. J. Solution Chem. 30, 909–923 (2001)

    Article  Google Scholar 

  4. Martínez, F., Gómez, A.: Thermodynamics of partitioning of some sulfonamides in 1-octanol/buffer and liposome systems. J. Phys. Org. Chem. 15, 874–880 (2002)

    Article  Google Scholar 

  5. Martínez, F., Gómez, A., Ávila, C.M.: Volúmenes molales parciales de transferencia de algunas sulfonamidas desde el agua hasta la mezcla agua-etanol (X=0.5). Acta Farm. Bonaerense 21, 107–118 (2002)

    Google Scholar 

  6. Pharmacopeia, U.S., 23rd. revision, p. 1456. The United States Pharmacopeial Convention, Inc., Rockville MD (1994)

  7. Kratky, O., Leopold, H., Stabinger, H.: DMA45 Calculating Digital Density Meter, Instruction Manual pp. 1–12. Anton Paar, K.G., Graz, Austria (1980)

    Google Scholar 

  8. Millero, F.J. In: Horne, R.A. (ed.) Water and Aqueous Solutions, pp. 519–564. Wiley, New York (1972),

    Google Scholar 

  9. Taylor, B.N., Kuyatt, C.E.: Guidelines for evaluating and expressing the uncertainty of NIST measurement results. Technical Note 1297, United States Department of Commerce, National Institute of Standards and Technology, Gaithersburg, MD (1994)

  10. Millero, F.J.: The molal volumes of electrolytes. Chem. Rev. 71, 147–176 (1971)

    Article  CAS  Google Scholar 

  11. Franks, F., Smith, H.T.: Apparent molal volumes and expansibilities of electrolytes in dilute aqueous solution. Trans. Faraday Soc. 63, 2586–2598 (1967)

    Article  CAS  Google Scholar 

  12. Wen, W.Y., Saito, S.: Apparent and partial molal volumes of five symmetrical tetraalkylammonium bromides in aqueous solutions. J. Phys. Chem. 68, 2639–2644 (1964)

    Article  CAS  Google Scholar 

  13. De Lisi, R., Milioto, S., Verrall, R.E.: Partial molar volumes and compressibilities of alkylmethylammonium bromides. J. Solution Chem. 19, 665–692 (1990)

    Article  Google Scholar 

  14. Blanco, L.H., Salamanca, Y.P., Vargas, E.F.: Apparent molal volumes and expansibilities of tetraalkylammonium bromides in dilute aqueous solutions. J. Chem. Eng. Data 53, 2770–2776 (2008)

    Article  CAS  Google Scholar 

  15. Iqbal, M., Verrall, R.E.: Apparent molar volume and adiabatic compressibility studies of aqueous solutions of some drug compounds at 25 °C. Can. J. Chem. 67, 727–735 (1989)

    Article  CAS  Google Scholar 

  16. Klofutar, C., Horvat, J., Rudan-Tasič, D.: Apparent molar volume and apparent molar expansibility of sodium saccharin, potassium acesulfame and aspartame. Acta Chim. Slov. 53, 274–283 (2006)

    CAS  Google Scholar 

  17. Torres, D.R., Blanco, L.H., Martinez, F., Vargas, E.F.: Apparent molal volumes of lidocaine–HCl and procaine–HCl in aqueous solution as a function of temperature. J. Chem. Eng. Data 52, 1700–1703 (2007)

    Article  CAS  Google Scholar 

  18. Cheema, M.A., Castro, E., Taboada, P., Siddiq, M., Mosquera, V.: Thermodynamic study of warfarin sodium salt: surface tension, conductivity, and density measurements. J. Chem. Eng. Data 52, 2315–2318 (2007)

    Article  CAS  Google Scholar 

Download references

Acknowledgements

We thank the DIB-DINAIN of the Universidad Nacional de Colombia (UNC) for financial support and the Department of Pharmacy of UNC for facilitating the required equipment and laboratory.

Author information

Authors and Affiliations

  1. Grupo de Investigaciones Farmacéutico-Fisicoquímicas, Departamento de Farmacia, Facultad de Ciencias, Universidad Nacional de Colombia, A.A., 14490, Bogotá D.C., Colombia

    Daniel R. Delgado & Fleming Martínez

  2. Laboratorio de Termodinámica de Soluciones, Departamento de Química, Facultad de Ciencias, Universidad de los Andes, Bogotá D.C., Colombia

    Edgar F. Vargas

Authors
  1. Daniel R. Delgado
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Edgar F. Vargas
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Fleming Martínez
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Fleming Martínez.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Delgado, D.R., Vargas, E.F. & Martínez, F. Apparent Molar Volumes of Some Sodium Sulfonamides in Water at Several Molalities and Temperatures. J Solution Chem 40, 1955–1963 (2011). https://doi.org/10.1007/s10953-011-9765-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10953-011-9765-4

Keywords

Search

Navigation