Abstract
Densities, ρ 123, and speeds of sound, u 123, of 1-methyl pyrrolidin-2-one (1) + benzene or methyl benzene or cyclohexane (2) + propan-2-ol (3) ternary mixtures have been measured over the entire composition range at 308.15 K and atmospheric pressure. The resulting ρ 123 and \(V_{123}^{\mathrm{E}}\) data were utilized to predict excess isentropic compressibilities, \((\kappa_{S}^{\mathrm{E}})_{123}\), of the studied (1+2+3) mixtures. The observed \(V_{123}^{\mathrm{E}}\) and \((\kappa_{S}^{\mathrm{E}})_{123}\) data have been analyzed in terms of Graph theory (which involved the topology of a molecule). It has been observed that \(V_{123}^{\mathrm{E}}\) and \((\kappa_{S}^{\mathrm{E}})_{123}\) values determined by Graph theory compare well with their corresponding experimental values.
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Chhikara, Y., Yadav, J.S., Sharma, D. et al. Thermodynamic Study of Ternary Mixtures Containing 1-Methyl Pyrrolidin-2-one, Propan-2-ol and Benzene or Methyl Benzene or Cyclohexane. J Solution Chem 40, 1769–1783 (2011). https://doi.org/10.1007/s10953-011-9751-x
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DOI: https://doi.org/10.1007/s10953-011-9751-x