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Study of the Surface Tensions of Binary Mixtures of Isomeric Chlorobutanes with Methyl tert-Butyl Ether

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Abstract

In the present work we report experimental surface tensions for binary mixtures of isomeric chlorobutanes with methyl tert-butyl ether from 283.15 to 303.15 K, measured with a drop volume tensiometer. From these experimental data the corresponding surface tension deviations were calculated and correlated using a Redlich-Kister type polynomial. Finally, we include the calculation of excess surface compositions for all of the mixtures from 288.15 K to 308.15 K.

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References

  1. Giner, B., Bandrés, I., Artigas, H., Cea, P., Lafuente, C.: Surface tension of mixtures of tetrahydrofuran or tetrahydropyran with isomeric chlorobutanes. Int. J. Thermophys. 28, 1188–1198 (2007)

    Article  CAS  Google Scholar 

  2. Royo, F.M., Villares, A., Martín, S., Giner, B., Lafuente, C.: Surface study of mixtures containing cyclic ethers and isomeric chlorobutanes. J. Chem. Thermodyn. 39, 791–797 (2007)

    Article  CAS  Google Scholar 

  3. Ihmels, E.C., Gmehling, J.: Compressed liquid densities of methyl tert-butyl ether (MTBE), ethyl tert-butyl ether (ETBE), and diisopropyl ether (DIPE). J. Chem. Eng. Data 47, 1307–1313 (2002)

    Article  CAS  Google Scholar 

  4. Ouyang, G., Guizeng, L., Pan, C., Yang, Y., Huang, Z., Kang, B.: Excess molar volumes and surface tension of xylene with isopropyl ether or methyl tert-butyl ether at 298.15 K. J. Chem. Eng. Data 49, 732–734 (2004)

    Article  CAS  Google Scholar 

  5. Wang, X., Pan, J., Wu, J., Liu, Z.: Surface tension of dimethoxymethane and methyl tert-butyl ether. J. Chem. Eng. Data 51, 1394–1397 (2006)

    Article  CAS  Google Scholar 

  6. Gonzalez-Olmos, R., Iglesias, M., Goegana, J.M., Resa, J.M.: Influence of temperature on thermodynamic properties of methyl tert-butyl ether (MTBE) + gasoline additives. Int. J. Thermophys. 28, 1199–1227 (2007)

    Article  CAS  Google Scholar 

  7. Suresh Reddy, K.V.N., Srinivasa Rao, P., Krishnaiah, A.: Experimental and theoretical values of sound speeds and viscosities for the binary systems of MTBE with hydrocarbons. J. Mol. Liq. 135, 14–20 (2007)

    Article  Google Scholar 

  8. Gonzalez-Olmos, R., Iglesias, M.: Influence of temperature on thermodynamics of ethers + xylenes. Fluid Phase Equilib. 267, 133–139 (2008)

    Article  CAS  Google Scholar 

  9. Miller, R., Hofmann, A., Hartmann, R., Schano, K.-H., Halbig, A.: Measuring dynamic surface and interfacial tensions. Adv. Mater. 4, 370–374 (1992)

    Article  CAS  Google Scholar 

  10. Spieweck, F., Bettin, H.: Review: solid and liquid density determination. Tech. Mess. 59, 285–292 (1992)

    CAS  Google Scholar 

  11. Timmermans, J.: Physico-Chemical Constants of Pure Organic Compounds, vol. II. Elsevier, Amsterdam (1965)

    Google Scholar 

  12. Kovacs, E., Aim, K., Linek, J.: Excess molar volumes of (an alkane + 1-chloroalkane) at T=298.15 K. J. Chem. Thermodyn. 33, 33–45 (2001)

    Article  CAS  Google Scholar 

  13. TRC: Thermodynamic Tables Hydrocarbons and Non-Hydrocarbons, Selected Values of Properties of Chemical Compounds, Thermodynamic Research Center, Texas A&M University College Station, TX (2011)

  14. Riddick, J.A., Bunger, W.B., Sakano, T.K.: Organic Solvents. Physical Properties and Methods of Purification, 4th edn. Wiley-Interscience, New York (1986)

    Google Scholar 

  15. Landaverde-Cortes, D., Iglesias-Silva, G., Ramos-Estrada, M., Hall, K.R.: Densities and viscosities of MTBE + nonane or decane at p=0.1 MPa from (273.15 to 363.15) K. J. Chem. Eng. Data 53, 288–292 (2008)

    Article  CAS  Google Scholar 

  16. Glinski, J., Chavepeyer, G., Platten, J.-K.: Surface properties of diluted aqueous solutions of normal propyl alcohol. J. Chem. Phys. 104, 8816–8820 (1996)

    Article  CAS  Google Scholar 

  17. Montaño, D.: PhD Thesis, University of Zaragoza (2011)

  18. Defay, R., Prigogine, I.: Surface Tension and Adsorption. Longmans, London (1966)

    Google Scholar 

  19. Privat, M., Bennes, R.: Conditions of phase separation, both at the interface (occasionally considered as a monolayer) and in solution for a binary liquid vapor system: The adsorption isotherm and the consequences of critical phenomena on the behavior of the system. J. Colloid Interface Sci. 90, 454–468 (1982)

    Article  CAS  Google Scholar 

  20. Motomura, K., Iyota, H., Ikeda, N., Aratono, M.: Thermodynamic studies on adsorption at interfaces. 6. Interface between cyclohexane benzene mixture and water. J. Colloid Interface Sci. 126, 26–36 (1988)

    Article  CAS  Google Scholar 

  21. Stery, R., Viisanen, Y., Aratono, M., Kratohvil, J.P., Yin, Q., Friberg, S.E.: On the necessity of using activities in the Gibbs equation. J. Phys. Chem. B 103, 9112–9116 (1999)

    Article  Google Scholar 

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Correspondence to Félix M. Royo.

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Montaño, D., Bandrés, I., Ballesteros, L.M. et al. Study of the Surface Tensions of Binary Mixtures of Isomeric Chlorobutanes with Methyl tert-Butyl Ether. J Solution Chem 40, 1173–1186 (2011). https://doi.org/10.1007/s10953-011-9717-z

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  • DOI: https://doi.org/10.1007/s10953-011-9717-z

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