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A Novel Attempt to Calculate the Velocity Correlation Coefficients in Ternary Electrolyte Solution

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Abstract

This work gives estimated values of the velocity correlation coefficients VCCs for ternary electrolyte solutions (the system may have a tracer ion as one of the components), utilizing available measured transport coefficients. The VCCs originate from linear response theory and give a deeper insight into the microdynamic structure of complex ionic solutions. By assuming Onsager’s relation to be valid, ten sets of velocity correlation coefficients were calculated for a ternary system and were used to calculate the VCCs for 134Cs+ ion (present in trace amount) transport in aqueous solutions of CsCl and KCl at 25 ○C.

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Authors and Affiliations

  1. Department of Physics, Lady Brabourne College, University of Calcutta, P-1/2 Suhrawardy Avenue, Kolkata, 700 017, India

    Haimanti Chakrabarti

  2. Department of Physics, Viswa Bharati University, P. O. Santiniketan, West Bengal, PIN 731235, India

    Shreekantha Sil

  3. Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata, 700 064, India

    Srinanda Kundu

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  1. Haimanti Chakrabarti
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  2. Shreekantha Sil
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  3. Srinanda Kundu
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Correspondence to Haimanti Chakrabarti.

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Chakrabarti, H., Sil, S. & Kundu, S. A Novel Attempt to Calculate the Velocity Correlation Coefficients in Ternary Electrolyte Solution. J Solution Chem 39, 1278–1290 (2010). https://doi.org/10.1007/s10953-010-9586-x

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