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Dielectric and Thermodynamic Studies on the Hydrogen Bonded Binary System of Isopropyl Alcohol and Aniline

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Abstract

The molecular interactions between the polar systems isopropyl alcohol (IPA) and aniline for various mole fractions at different temperatures were studied by determining the dielectric permittivity using an HP-LF impedance analyzer at radio frequencies, the plunger method in the microwave frequency range and Abbe’s refractometer in optical region. Kirkwood effective correlation factors, corrective Kirkwood correlation factors, excess permittivities, Bruggeman parameters, excess Helmholtz free energy, relaxation time, dipole moment and excessive dipole moment were calculated using the experimental data. Optimized geometries were calculated using Spartan Modeling software for both pure and equimolar systems of isopropyl alcohol and aniline for Hamiltonian quantum mechanical calculations. Conformational analysis of the formation of hydrogen bond between the two systems is supported by the FT-IR spectra.

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References

  1. Gupta, K.K., Bnashal, A.K., Singh, P.J., Sharma, K.S.: Temperature dependence of dielectric relaxation of rigid polar molecules acetophenone, pyridine and their mixtures in dilute solutions of benzene. Indian J. Pure Appl. Phys. 41, 57–63 (2003)

    CAS  Google Scholar 

  2. Reddy, R.R., Rama Gopal, K., Narasimhulu, K., Siva Sankara Reddy, L., Raghavendra Kumar, K., Venkatesulu, A., Krishna Reddy, C.V.: Correlations between Moelwyn–Hughes parameter, available volume and intermolecular free-lengths in liquid systems. J. Mol. Liq. 140, 48–53 (2008)

    Article  CAS  Google Scholar 

  3. Thenappan, T., Subramanian, M.: Studies on fluid structure and molecular interactions of amines. Indian J. Pure Appl. Phys. 39, 694–697 (2001)

    CAS  Google Scholar 

  4. Ghanadzaaeh, A., Ghanadzadeh, H., Sariri, R., Ebrahimi, L.: Dielectric study of molecular association in the binary mixtures (2-ethyl-1-hexanol + alcohol) and (cyclohexane + alcohol) at 298.2 K. J. Chem. Thermodyn. 37, 357–362 (2005)

    Article  Google Scholar 

  5. Nath, G., Sahu, S., Paikaray, R.: Study of acoustic parameters of binary mixtures of a nonpolar liquid with polar liquid at different frequencies. Indian J. Phys. 83, 429–436 (2009)

    Article  CAS  Google Scholar 

  6. Kroeger, M.K.: Clustering and dielectric behavior of alcohols. J. Mol. Liq. 36, 101–118 (1987)

    Article  CAS  Google Scholar 

  7. Sengwa, R.J., Vinita, K., Sonu, S.: Static dielectric constants and Kirkwood correlation factor of the binary mixtures of N-ethylformamide with formamide, N,N-dimethylformamide and N,N-dimethylacetamide. J. Solution Chem. 38, 763–769 (2009)

    Article  CAS  Google Scholar 

  8. George, A.J.: An Introduction to Hydrogen Bonding. Oxford University Press, Oxford (1997)

    Google Scholar 

  9. Vishwam, T., Subramanian, V., Subbaiah, D.V., Murthy, V.R.K.: Conformational and microwave dielectric relaxation studies of hydrogen bonded polar binary mixtures of propionaldehyde with isopropyl amine. Mol. Phys. 106, 95–101 (2008)

    Article  CAS  Google Scholar 

  10. Cole, K.S., Cole, R.H.: Dispersion and absorption in dielectrics I. Alternating current characteristics. J. Chem. Phys. 9, 341–351 (1941)

    Article  CAS  Google Scholar 

  11. Sharma, B.S., Venkateswara Rao, V.: An empirical relation for the evaluation of the dielectric relaxation time of certain polar liquids using a single microwave frequency. Aust. J. Phys. 27, 87–91 (1974)

    Google Scholar 

  12. Parthipan, G., Arivazhagan, G., Thenappan, T.: Dielectric and thermodynamic studies on a binary mixture of anisole with butyric or caprylic acid. Philos. Mag. Lett. 88, 125–136 (2008)

    Article  CAS  Google Scholar 

  13. Higasi, K.A., Koga, Y., Nakamura, M.: Dielectric relaxation and molecular structure. V. Application of the single frequency method to systems with two Debye dispersions. Bull. Chem. Soc. 44, 988–992 (1971)

    Article  CAS  Google Scholar 

  14. Sathyan, N., Santhanam, V., Madhurima, V., Sobhanadri, J.: Conformational study on the binary mixture acetone-methanol involving H-bonding. J. Mol. Struct. (Theochem) 342, 187–192 (1995)

    Article  CAS  Google Scholar 

  15. Chitra, M., Subramanyam, B., Murthy, V.R.K.: Conformational and dielectric analysis of hydrogen bonded polar binary mixtures of methyl benzoate with aniline. Indian J. Pure Appl. Phys. 39, 461–466 (2001)

    CAS  Google Scholar 

  16. Hill, N.E., Vaughan, W.E., Price, A.H., Davies, M.: Dielectric Properties and Molecular Behavior. Van Nostrand-Reinhold, London (1969)

    Google Scholar 

  17. Lide, D.R.: CRC. Handbook of Chemistry and Physics, 78th edn. CRC Press, Boca Raton (1971)

    Google Scholar 

  18. Kirkwood, J.G.: The dielectric polarization of polar liquids. J. Chem. Phys. 7, 911–919 (1939)

    Article  CAS  Google Scholar 

  19. Kumbharkhane, A.C., Puranik, S.M., Mehrotra, S.C.: Dielectric relaxation studies of aqueous N,N-dimethylformamide using picosecond time domain technique. J. Solution Chem. 22, 219–229 (1993)

    Article  CAS  Google Scholar 

  20. Luzar, A., Stefan, J.: Dielectric behaviour of DMSO-water mixtures: a hydrogen-bonding model. J. Mol. Liq. 46, 221–238 (1990)

    Article  CAS  Google Scholar 

  21. Bruggeman, D.A.G.: Berechnung verschiedener physikalischer Konstanten von heterogenen Substanzen. Ann. Physik 24, 636–644 (1935)

    Article  CAS  Google Scholar 

  22. Gupta, K.K., Basal, A.K., Singh, P.J., Sharma, K.S.: Study of molecular interactions in binary mixtures of acetophenone derivative and cyclohexylamine. Indian J. Phys. 79, 147–152 (2005)

    CAS  Google Scholar 

  23. Vishwam, T., Chitra, M., Subramanian, V., Murthy, V.R.K.: Experimental and theoretical analysis of hydrogen bonded polar system of isobutanol and isobutyraldehyde. J. Mol. Liq. 135, 90–95 (2007)

    Article  CAS  Google Scholar 

  24. Thenappan, T., Prabakar, Devaraj: A.: Dielectric studies on binary polar mixtures of propanoic acid with esters. J. Mol. Liq. 123, 72–79 (2006)

    Article  CAS  Google Scholar 

  25. Chaudhari, A., Antia, D., Raju, G., Chaudhari, H., Prakash, K., Navinkumar, N., Suresh, M.: Complex permittivity spectra of binary mixture of ethanol with nitrobenzene and nitrotoluene usuing the time domain technique. Proc. Natl. Sci. Counc, ROC A. 25, 205–210 (2001)

    CAS  Google Scholar 

  26. Balamurugan, D., Kumar, S., Krishnan, S.: Dielectric relaxation studies of higher order alcohol complexes with amines using time domain reflectometry. J. Mol. Liq. 122, 11–14 (2005)

    Article  CAS  Google Scholar 

  27. Pawar, V.P., Patil, A.R., Mehrotra, S.C.: Temperature-dependent dielectric relaxation study of chlorobenzene with n-methylformamide from 10 MHz to 20 GHz. J. Mol. Liq. 121, 88–93 (2005)

    Article  CAS  Google Scholar 

  28. Rana, V.A., Vyas, A.D., Mehrotra, S.C.: Dielectric relaxation study of mixtures of 1-propanol with aniline, 2-chloroaniline and 3-chloroaniline at different temperatures using time domain reflectometry. J. Mol. Liq. 102, 379–391 (2002)

    Article  Google Scholar 

  29. Sengwa, R.J., Madhvi Sonu, S., Shobha, S.: Characterization of heterogeneous interaction behavior in ternary mixtures by a dielectric analysis: equimolar H-bonded binary polar mixtures in aqueous solutions. J. Solution Chem. 35, 1037 (2006)

    Article  CAS  Google Scholar 

  30. Sivagurunathan, P., Dharmalingam, K., Ramachandran, K., Prabhakar, U.B., Khirade, P.W., Mehrotra, S.C.: Dielectric studies on binary mixtures of ester with alcohol using time domain reflectometry. J. Mol. Liq. 133, 139–145 (2007)

    Article  CAS  Google Scholar 

  31. Vishwam, T., Chitra, M., Subramanian, V., Murthy, V.R.K.: Conformational and dielectric analysis of Hydrogen bonded polar binary mixtures of propan-1-ol with propionaldehyde. Mol. Phys. 105, 2411–2417 (2007)

    Article  CAS  Google Scholar 

  32. Satheesh, V., Jayaraj, M., Sobhanadri, J.: Dielectric studies of allyl alcohol with (i) pyridine, (ii) 1,4-dioxane and (iii) phenol hydrogen bonded complexes. J. Mol. Liq. 64, 247–261 (1995)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Physics, Vasireddy Venkatadri Institute of Technology, Nambur, 522508, India

    T. Vijaya Krishna

  2. Department of Physics, Acharya Nagarjuna University, Nagarjunanagar, 522510, India

    S. Sreehari Sastry

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  1. T. Vijaya Krishna
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Correspondence to S. Sreehari Sastry.

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Krishna, T.V., Sastry, S.S. Dielectric and Thermodynamic Studies on the Hydrogen Bonded Binary System of Isopropyl Alcohol and Aniline. J Solution Chem 39, 1377–1393 (2010). https://doi.org/10.1007/s10953-010-9583-0

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  • DOI: https://doi.org/10.1007/s10953-010-9583-0

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