Abstract
A recently developed model for predicting the thermodynamic properties of electrolytes to high temperatures and pressures, the unified theory of electrolytes, is used to calculate the solubility product of lithium metaborate in acid solutions from 298.15 K to T c. The results are compared with the available high temperature experimental data in the literature. This study also establishes a value of Δf H ○ (298.15 K,0.1 MPa) for LiBO2(cr) that is in good agreement with the JANAF tables value.
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Djamali, E., Turner, P.J. Solubility Product for Lithium Metaborate in Acid Solutions to Extreme Temperatures and Pressures. J Solution Chem 39, 820–827 (2010). https://doi.org/10.1007/s10953-010-9547-4
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DOI: https://doi.org/10.1007/s10953-010-9547-4