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Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N2O2 Donor Ligands Derived from 4,4′-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde

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Abstract

The condensation of 2-hydroxybenzaldehyde or 2,4-dihydroxybenzaldehyde with 4,4′-diaminobiphenyl in absolute EtOH in a molar ratio 2:1 gave, respectively, the Schiff base ligands H2L1 or H2L2. The bases served as tetradentate ligands to coordinate CoII, NiII and CdII chlorides, leading to complexes where the metal:ligand ratio is 2:1. All of the compounds were characterized by elemental analysis, infrared, electronic and mass spectroscopy, 1H-n.m.r. and d.s.c. The cyclic voltammograms of the ligands and their complexes in DMF are discussed.

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Authors and Affiliations

  1. Département de Génie des Procédés, Faculté des Sciences de l’Ingénieur, Université Ferhat Abbas, Sétif, 19000, Algeria

    Lakhdar Sibous, Embarek Bentouhami & Amor Maïza

  2. Chimie de Coordination, Faculté de Pharmacie, Université d’Angers, 16 Boulevard Daviers, 49045, Angers Cedex 01, France

    Gilles M. Bouet & Mustayeen Ahmed Khan

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  1. Lakhdar Sibous
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  2. Embarek Bentouhami
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  3. Amor Maïza
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  4. Gilles M. Bouet
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  5. Mustayeen Ahmed Khan
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Correspondence to Mustayeen Ahmed Khan.

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Sibous, L., Bentouhami, E., Maïza, A. et al. Synthesis, Characterization and Electrochemical Behavior of CoII, NiII and CdII Complexes with N2O2 Donor Ligands Derived from 4,4′-Diaminobiphenyl and 2-Hydroxybenzaldehyde or 2,4-Dihydroxybenzaldehyde. J Solution Chem 39, 511–521 (2010). https://doi.org/10.1007/s10953-010-9512-2

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