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Excess Volumes, Isentropic Compressibilities and Viscosities for Binary Mixtures of tert-Butylamine with Alkyl Acetates at 303.15 K

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Abstract

The data on excess volume (V E), density (ρ), viscosity (η) and speeds of sound (u) for the binary mixtures of tert-butylamine (TBA) + methyl acetate (MA), + ethyl acetate (EA), + butyl acetate (BA) and + isoamyl acetate (IAA) at 303.15 K were measured experimentally over the entire range of composition. Speeds of sound were evaluated using Jacobson’s free length theory (FLT) and Schaaffs’ collision factor theory (CFT). The viscosity data were analyzed on the basis of the corresponding states approach and the Grunberg and Nissan treatment. The experimental results for excess volume, deviation in isentropic compressibility and deviation in viscosity were discussed in terms of molecular interactions between unlike molecules. A Redlich-Kister type equation was used to fit the experimental data on excess volume, deviation in compressibility and deviation in viscosity.

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References

  1. Resa, J.M., Gonzalez, C., Goenaga, J.M., Iglesias, M.: Temperature dependence of excess molar volumes of ethanol + water + ethyl acetate. J. Solution Chem. 33, 169–198 (2004)

    Article  CAS  Google Scholar 

  2. Kinart, C.M., Kinart, W.J., Checinska-Majak, D., Cwiklinsk, A.: Volumetric behaviour of binary liquid mixtures of 2-methoxyethanol with n-butylamine, sec-butylamine and tert-butylamine. J. Mol. Liq. 109, 19–22 (2004)

    Article  CAS  Google Scholar 

  3. Kinart, C.M., Kinart, W.J., Checinska-Majak, D., Cwiklinsk, A.: Refractive properties of binary mixtures containing 2-methoxyetanol and n-butylamine, isobutylamine, sec-butylamine and tert-butylamine. Phys. Chem. Liq. 41, 383–389 (2003)

    Article  CAS  Google Scholar 

  4. Subha, M.C.S., Swamy, G.N., Bai, M.E., Rao, K.S.V.K.: Excess volume and viscosity of ethoxy ethanol with n-butylamine, sec-butylamine, tert-butylamine, n-hexylamine, n-octylamine and cyclohexylamine. Ind. J. Chem. 43A, 1876–1881 (2004)

    CAS  Google Scholar 

  5. Kipkemboi, P.K., Easteal, A.J.: Densities and viscosities of binary aqueous mixtures of nonelectrolytes: tert-butyl alcohol and tert-butylamine. Can. J. Chem. 72, 1937–1945 (1994)

    Article  CAS  Google Scholar 

  6. Bayles, J.W., Letcher, T.M.: Thermodynamics of some binary liquid mixtures containing aliphatic amines. J. Chem. Eng. Data 16, 266–271 (1971)

    Article  CAS  Google Scholar 

  7. Sastry, N.V., Patel, M.C.: Densities, excess molar volumes, viscosities, speeds of sound, excess isentropic compressibilities, and relative permittivities for alkyl (methyl, ethyl, butyl, and isoamyl) acetates + glycols at different temperatures. J. Chem. Eng. Data 48, 1019–1027 (2003)

    Article  CAS  Google Scholar 

  8. Riddick, J.A., Bunger, W.B.: Techniques of Chemistry, vol. II, 3rd edn. Wiley-Interscience, New York (1970)

    Google Scholar 

  9. TRC—Thermodynamic Tables—Non-Hydrocarbons: Thermodynamics Research Centre, The Texas A&M University System: College Station, TX 1963; a-6060 (Loose-leaf data sheets, extant 1996)

  10. Reddy, K.V., Rambabu, K., Devarajulu, T., Krishnaiah, A.: Volume of mixing, speed of sound, and viscosity of methyl cellosolve with aliphatic alcohols at 308.15 K. J. Chem. Eng. Data 40, 124–127 (1995)

    Article  CAS  Google Scholar 

  11. Rao, M.V.P., Naidu, P.R.: Excess volumes of binary mixtures of alcohols in methylcyclohexane. Can. J. Chem. 52, 788–790 (1974)

    Article  CAS  Google Scholar 

  12. Krishnaiah, A., Surendranath, K.N.: Densities, speeds of sound, and viscosities of mixtures of oxolane with chloroethanes and chloroethenes. J. Chem. Eng. Data 41, 1012–1014 (1996)

    Article  CAS  Google Scholar 

  13. Oswal, S.L., Phalak, R.P.: Speed of sound and isentropic compressibilities of nonelectrolyte liquid mixtures. I. Binary mixtures containing p-dioxane. J. Solution Chem. 22, 43–58 (1993)

    Article  CAS  Google Scholar 

  14. Jacobson, B.: Ultrasonic velocity in liquids and liquid mixtures. J. Chem. Phys. 20, 927–928 (1952)

    Article  CAS  Google Scholar 

  15. Schaaffs, W.: Problem of a theoretical calculation of the velocity of sound for binary liquid mixtures. Acustica 33, 272–276 (1975)

    CAS  Google Scholar 

  16. Reddy, K.V.N.S., Rao, P.S., Krishnaiah, A.: Experimental and theoretical values of sound speeds and viscosities for the binary systems of MTBE with hydrocarbons. J. Mol. Liq. 135, 14–20 (2007)

    Article  CAS  Google Scholar 

  17. Jacobson, B.: Intermolecular free lengths in liquids in relation to compressibility, surface tension and viscosity. Acta Chem. Scand. 5, 1214–1216 (1951)

    Article  CAS  Google Scholar 

  18. Teja, A.S., Rice, P.: The measurement and prediction of the viscosities of some binary liquid mixtures containing n-hexane. Chem. Eng. Sci. 36, 7–10 (1981)

    Article  CAS  Google Scholar 

  19. Teja, A.S., Rice, P.: Generalized corresponding states method for the viscosities of liquid mixtures. Ind. Eng. Chem. Fundam. 20, 77–81 (1981)

    Article  CAS  Google Scholar 

  20. Krishnaiah, A., Viswanath, D.S.: Densities, viscosities, and excess volumes of isopropyl acetate + cyclohexane mixtures at 298.15 and 308.15 K. J. Chem. Eng. Data 36, 317–318 (1991)

    Article  CAS  Google Scholar 

  21. Grunberg, L., Nissan, A.H.: Mixture law for viscosity. Nature 164, 799–800 (1949)

    Article  CAS  Google Scholar 

  22. Reddy, K.V., Reddy, K.S., Krishnaiah, A.: Excess volumes, speeds of sound, and viscosities for mixtures of 1,2-ethanediol and alkoxy alcohols with water at 308.15 K. J. Chem. Eng. Data 39, 615–617 (1994)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Biopolymers and Thermophysical Laboratory, Department of Chemistry, Sri Venkateswara University, Tirupati, 517502, India

    G. Sankara Reddy, A. Subba Reddy, M. Venkata Subbaiah & A. Krishnaiah

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  1. G. Sankara Reddy
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  2. A. Subba Reddy
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  3. M. Venkata Subbaiah
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  4. A. Krishnaiah
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Correspondence to A. Krishnaiah.

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Reddy, G.S., Reddy, A.S., Subbaiah, M.V. et al. Excess Volumes, Isentropic Compressibilities and Viscosities for Binary Mixtures of tert-Butylamine with Alkyl Acetates at 303.15 K. J Solution Chem 39, 399–408 (2010). https://doi.org/10.1007/s10953-010-9509-x

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