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Complex Formation of Crown Ethers and Cations in Water–Organic Solvent Mixtures: Part XI. Effects of the Preferential Solvation of Benzo-15-Crown-5 and Acid-Base Properties of the Mixtures on the Thermodynamic Functions for Complex Formation of Benzo-15-Crown-5 with Na+ in Propan-1-ol–Water Mixtures at 298.15 K

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An Erratum to this article was published on 01 December 2009

Abstract

The thermodynamic functions of complex formation of benzo-15-crown-5 ether (B15C5) and sodium cation (Na+) in the mixtures of propan-1-ol (PrOH) with water at 298.15 K have been calculated from experimental measurements. The equilibrium constants of B15C5/Na+ complex formation have been determined by conductivity measurements. The enthalpic effect of complex formation has been measured by a calorimetric method. The complexes are enthalpy stabilized but entropy destabilized in the PrOH–H2O mixtures. The effects of preferential solvation of B15C5 by molecules of the organic solvent, solvation of the sodium cation, as well as the acid-base properties of propan-1-ol–water mixtures on the complex formation processes are discussed.

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Authors and Affiliations

  1. Department of Physical Chemistry, University of Lodz, ul. Pomorska 165, 90-236, Lodz, Poland

    Małgorzata Jóźwiak

  2. Department of Physical Chemistry of Solutions, University of Lodz, ul. Pomorska 163, 90-236, Lodz, Poland

    Adam Bald

  3. Department of Organic Chemistry, University of Lodz, ul. Narutowicza 68, 90-136, Lodz, Poland

    Andrzej Jóźwiak

Authors
  1. Małgorzata Jóźwiak
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  2. Adam Bald
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  3. Andrzej Jóźwiak
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Correspondence to Małgorzata Jóźwiak.

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An erratum to this article can be found at http://dx.doi.org/10.1007/s10953-009-9460-x

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Jóźwiak, M., Bald, A. & Jóźwiak, A. Complex Formation of Crown Ethers and Cations in Water–Organic Solvent Mixtures: Part XI. Effects of the Preferential Solvation of Benzo-15-Crown-5 and Acid-Base Properties of the Mixtures on the Thermodynamic Functions for Complex Formation of Benzo-15-Crown-5 with Na+ in Propan-1-ol–Water Mixtures at 298.15 K. J Solution Chem 38, 1283–1294 (2009). https://doi.org/10.1007/s10953-009-9446-8

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