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Studies of Partial Molar Volumes of Alkylamines in Non-electrolyte Solvents. IV. Alkyl Amines in Cyclic Ethers at 303.15 K

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Abstract

Apparent molar volumes V φ,B of n-propylamine, n-butylamine, di-n-propylamine, di-n-butylamine, triethylamine, tri-n-propylamine, and tri-n-butylamine in 1,4-dioxane and in oxolane (tetrahydrofuran) have been determined at 303.15 K using a high-precision Anton Paar vibrating-tube densimeter (model DMA 60/602). The limiting partial molar volumes \(\overline{V}_{\mathrm{B}}^{\infty}\) and limiting excess partial molar volumes \(\overline{V}_{\mathrm{B}}^{\mathrm{E},\infty}\) are analyzed and interpreted in terms of solute-solvent interactions and structural effects of the molecules.

Analyses were made of the contributions of specific interactions to the partial molar volumes of these primary, secondary and tertiary amines in 1,4-dioxane and oxolane using the Terasawa model, scaled particle theory (SPT) and hard-sphere theory (HST). The ERAS model has also been applied to estimate the apparent molar volumes and excess apparent molar volumes of alkylamine solutions in 1,4-dioxane and oxolane.

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  1. Biochemistry Division, R. & D. Span Diagnostic Limited, 173-B, New Industrial Estate, Udhna, Surat, 394210, India

    S. L. Oswal

  2. Department of Chemistry, S.V. National Institute of Technology, Surat, 395 007, India

    S. P. Ijardar

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Oswal, S.L., Ijardar, S.P. Studies of Partial Molar Volumes of Alkylamines in Non-electrolyte Solvents. IV. Alkyl Amines in Cyclic Ethers at 303.15 K. J Solution Chem 38, 321–344 (2009). https://doi.org/10.1007/s10953-009-9376-5

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