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Complexation of Sc(III), Ga(III), In(III) and Ln(III) with Eriochrome Red B

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Abstract

Cyclic linear-sweep voltammetry was used to study the complexation of Sc(III), Ga(III), In(III) and Ln(III) with eriochrome red B (ERB). It was established that all metal ions investigated form complex compounds with azodye having a mole ratio, M(III):ERB = 1:2. The hydroxo forms of M(III) ions, which take part in interaction with ERB, were determined by the Nazarenko method. The stability constants for the formation of these chelates are nearly the same. It was shown that the reduction of the ligand in the complex does not only depend on the peculiarities of complexation, but the processes occurring in pre-electrode layer also influence it.

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References

  1. Bishop, E.: Indicators. Pergamon Press, Oxford, New York, Toronto, Sydney, Braunschweig (1972)

    Google Scholar 

  2. Dubenskaya, L., Levytskaya, G., Poperechnaya, N.: Voltammetric reduction of In(III)-Eriochrome Red B complexes. J. Anal. Chem. 11, 1052–1055 (2005)

    Article  Google Scholar 

  3. Levytska, G., Tymoshuk, S., Bilyk, O.: Voltammetry of Co(II), Ni(II), Pd(II) and Zr(IV) ions with azodyes. Ann. Pol. Chem. Soc. 3, 326–329 (2004)

    Google Scholar 

  4. Levitskaya, G.D., Poperechnaya, N.P., Dubenskaya, L.O.: Polarographic behavior of Eriochrome Red B and its complexes with rare-earth ions. J. Anal. Chem. 6, 552–556 (2001)

    Article  Google Scholar 

  5. Çakir, O., Çoşkun, E., Biçer, E., Çakir, S.: Voltammetric and polarographic studies of Eriochrome Black T–nickel(II) complex. Turk. J. Chem. 25, 33–38 (2001)

    Google Scholar 

  6. Baes, C.F. Jr., Mesmer, R.E.: The Hydrolysis of Cations. Wiley, New York (1976)

    Google Scholar 

  7. Nazarenko, V.A., Antonovych, V.P.: Spectrophotometric determination of hydrolysis constants of gallium ions. Russ. J. Inorg. Chem. 13, 1574–1580 (1968)

    CAS  Google Scholar 

  8. Inczédy, J.: Analytical Applications of Complex Equilibria. Akadémiai Kiadó, Budapest (1976)

    Google Scholar 

  9. Florence, T.M., Belew, W.L.: Interpretation of the polarographic behaviour of metalsolochrome Violet RS complex. J. Electroanal. Chem. 21, 157–167 (1969)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Chemistry, Ivan Franko National University of L’viv, Kyryla and Mephodia Str. 6, 79005, L’viv, Ukraine

    S. Pysarevska, L. Dubenska & H. Levytska

Authors
  1. S. Pysarevska
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  2. L. Dubenska
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  3. H. Levytska
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Correspondence to S. Pysarevska.

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Pysarevska, S., Dubenska, L. & Levytska, H. Complexation of Sc(III), Ga(III), In(III) and Ln(III) with Eriochrome Red B. J Solution Chem 37, 1809–1818 (2008). https://doi.org/10.1007/s10953-008-9342-7

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  • DOI: https://doi.org/10.1007/s10953-008-9342-7

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