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Theoretical Description of Excess Molar Functions in the Case of Very Small Excess Values. Investigation of Excess Molar Volumes of Propan-2-ol + Alkanol Mixtures

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Abstract

The densities of propan-2-ol + pentan-1-ol, + hexan-1-ol, + heptan-1-ol, + octan-1-ol + nonan-1-ol and speeds of sound in propan-2-ol + pentan-1-ol, + heptan-1-ol, + nonan-1-ol have been measured over the whole composition range at 298.15 K. Excess molar functions determined from the experimental data have been plotted as functions of composition. The excess molar volumes have been interpreted on the basis of the Symmetrical Extended Real Associated Solution Model (S-ERAS).

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References

  1. Abe, A., Flory, P.J.: The thermodynamic properties of mixtures of small, nonpolar molecules. J. Am. Chem. Soc. 87, 1838–1846 (1965)

    Article  CAS  Google Scholar 

  2. Amigo, A., Bravo, R., Pintos, M.: Excess volumes of binary mixtures containing cyclic ethers + alkanols at 298.15 K. J. Chem. Eng. Data 38, 141–142 (1993)

    Article  CAS  Google Scholar 

  3. Aminabhavi, T.M., Aralaguppi, M.I., Harogoppad, S.B., Balundgi, R.H.: Densities, viscosities, refractive indices and speeds of sound for methyl acetoacetate + aliphatic alcohols (C1–C8). J. Chem. Eng. Data 38, 31–39 (1993)

    Article  CAS  Google Scholar 

  4. Aznarez, S.B., Postigo, M.A.: Excess molar volumes of binary mixtures of acetonitrile with n-alkanols at 25 °C. J. Solution Chem. 27, 1045–1054 (1998)

    Article  CAS  Google Scholar 

  5. Bender, M., Heintz, A.: Thermodynamics of 1-alkanol + n-alkane mixtures based on predictions of the ERAS model. Fluid Phase Equilib. 89, 197–215 (1993)

    Article  CAS  Google Scholar 

  6. Benson, G.-C., Pflug, H.-D.: Molar excess volumes of binary systems of normal alcohols at 25 °C. J. Chem. Eng. Data 15, 382–386 (1970)

    Article  CAS  Google Scholar 

  7. Bondi, A.: Physical Properties of Molecular Crystals, Liquids, and Glasses. Willey, New York, London, Sydney (1968)

    Google Scholar 

  8. Canosa, J., Rodriguez, A., Tojo, J.: Speeds of sound and dynamic viscosities of the ternary mixtures methyl acetate + methanol + 1-butanol or 1-pentanol and their corresponding binary mixtures at 298.15 K. J. Chem. Eng. Data 45, 471–477 (2000)

    Article  CAS  Google Scholar 

  9. Castro, I., Calvo, E., Bravo, R., Pintos, M., Amigo, A.: Excess volumes of ternary mixtures containing tetrahydropyran and decane with 1-alkanols at the temperature 298.15 K. J. Chem. Eng. Data 40, 230–232 (1995)

    Article  CAS  Google Scholar 

  10. de Cominges, B.E., Pineiro, M.M., Iglesias, T.P., Legido, J.L., Paz Andrade, M.I.: Refractive indices and speeds of sound of binary mixtures of n-hexane with 1-alkanol at the temperature 298.15 K. J. Chem. Thermodyn. 30, 1147–1157 (1998)

    Article  Google Scholar 

  11. Dewan, R.K., Mehta, S.K., Parashar, R.: Topological investigations on the association of alkanols: excess volume of pyridine–alkanol (C1–C10) mixtures. J. Chem. Soc. Faraday Trans. 87, 1561–1568 (1991)

    Article  CAS  Google Scholar 

  12. Diaz Pena, M., Tardajos, G.: Isothermal compressibilities of n−1-alcohols from methanol to 1-dodecanol at 298.15, 308.15, 318.15, and 333.15 K. J. Chem. Thermodyn. 11, 441–445 (1979)

    Article  CAS  Google Scholar 

  13. Domańska, U., Venkatesu, P.: Measurement and correlation of solid-liquid equilibria of 18-crown-6 in alcohols. J. Chem. Eng. Data 43, 919–924 (1998)

    Article  Google Scholar 

  14. Dzida, M.: Speeds of sound, densities, isobaric thermal expansion, compressibilities, and internal pressures of heptan-1-ol, octan-1-ol, nonan-1-ol, and decan-1-ol at temperatures from (293 to 318) K and pressures up to 100 MPa. J. Chem. Eng. Data 52, 521–531 (2007)

    Article  CAS  Google Scholar 

  15. El-Banna, M.M.: Densities and viscosities for mixtures of pentyl acetate and hexyl acetate with normal alkanols at 298.15 K. J. Chem. Eng. Data 42, 31–34 (1997)

    Article  CAS  Google Scholar 

  16. Ernst, S., Marczak, W., Manikowski, R., Zorębski, E., Zorębski, M.: A sing-around apparatus for group velocity measurements in liquids. Testing by standard liquids and discussion of the errors. Acoust. Lett. 15, 123–130 (1992)

    CAS  Google Scholar 

  17. Fernandez, J., Pintos, M., Baluja, M.C., Jimenez, E., Paz Andrade, M.I.: Excess enthalpies of some ester + alcohol binary mixtures. J. Chem. Eng. Data 30, 318–320 (1985)

    Article  CAS  Google Scholar 

  18. Flory, P.J.: Statistical thermodynamics of liquid mixtures. J. Am. Chem. Soc. 87, 1833–1838 (1965)

    Article  CAS  Google Scholar 

  19. Flory, P.J., Orwoll, R.A., Vrij, A.: Statistical thermodynamics of chain molecule liquids. I. An equation of state for normal paraffin hydrocarbons. J. Am. Chem. Soc. 86, 3507–3514 (1964)

    Article  CAS  Google Scholar 

  20. Flory, P.J., Orwoll, R.A., Vrij, A.: Statistical thermodynamics of chain molecule liquids. II. Liquid mixtures of normal paraffin hydrocarbons. J. Am. Chem. Soc. 86, 3515–3520 (1964)

    Article  CAS  Google Scholar 

  21. Francesconi, R., Comelli, F.: Excess molar enthalpies, densities, and excess molar volumes of diethyl carbonate in binary mixtures with seven n-alkanols at 298.15 K. J. Chem. Eng. Data 42, 45–48 (1997)

    Article  CAS  Google Scholar 

  22. Franjo, C., Jimenez, E., Iglesias, T.P., Legido, J.L., Paz Andrade, M.I.: Viscosities and densities of hexane + butan-1-ol, hexan-1-ol, and octan-1-ol at 298.15 K. J. Chem. Eng. Data 40, 68–70 (1995)

    Article  CAS  Google Scholar 

  23. Garcia, B., Aparicio, S., Nawarro, A.M., Alcalde, R., Leal, J.M.: Measurements and modeling of thermophysical behavior of (C1–C4) alkylbenzoate/ (C1–C11) alkan-1-ol mixed solvents. J. Phys. Chem. B 108, 15841–15850 (2004)

    Article  CAS  Google Scholar 

  24. Gepert, M.: Akustyczne i termodynamiczne właściwości wybranych binarnych mieszanin alkoholi oraz ich homomorfów: pentan-1-ol + oktan-1-ol, pentan-1-ol + n-nonan i n-heksan + n-nonan. Doctoral Thesis, Katowice (2001)

  25. Gepert, M., Ernst, S.: Interpretation of the excess molar volumes and excess molar compressions of pentan-1-ol + octan-1-ol mixtures on the basis of the Homomorph Concept. J. Solution Chem. 32, 831–852 (2003)

    Article  CAS  Google Scholar 

  26. Gepert, M., Hachuła, B.: Thermodynamic properties of binary mixtures of two alcohols. An application of the SERAS model to the description of very small excess molar functions. J. Mol. Liq. 135, 196–206 (2007)

    Article  CAS  Google Scholar 

  27. Gepert, M., Stachowska, B.: Experimental and theoretical description of binary mixtures containing monohydric alcohols. J. Solution Chem. 35, 425–454 (2006)

    Article  CAS  Google Scholar 

  28. Gonzalez, B., Dominguez, J., Tojo, J.: Viscosities, densities and speeds of sound of the binary system: 2-propanol with octane, or decane, or dodecane at T=(293.15,298.15 and 303.15) K. J. Chem. Thermodyn. 35, 939–953 (2003)

    Article  CAS  Google Scholar 

  29. Hales, J.L., Ellender, J.H.: Liquid densities from 293 to 490 K of nine aliphatic alcohols. J. Chem. Thermodyn. 8, 1177–1184 (1976)

    Article  CAS  Google Scholar 

  30. Heintz, A.: New theoretical approach for predicting excess properties of alkanol/alkane mixtures. Ber. Bunsenges. Phys. Chem. 89, 172–181 (1985)

    CAS  Google Scholar 

  31. Heintz, A., Schmittecker, B., Wagner, D., Lichtenthaler, R.N.: Excess volumes of binary 1-alkanol/hexane mixtures at temperatures between 283.15 and 323.15 K. J. Chem. Eng. Data 31, 487–492 (1986)

    Article  CAS  Google Scholar 

  32. Hetu, D., Perron, G.: Volumes of mixtures of alcohols in water at 25 °C. J. Solution Chem. 20, 207–220 (1991)

    Article  CAS  Google Scholar 

  33. Iglesias, T.P., Legido, J.L., Romani, L., Peleteiro, J., Franjo, C.: Relative permittivities, densities, and excess molar volumes of {xCH3(CH2)4CH3+(1−x)CH3(CH2)vOH} (v=2, 4 and 6) at the temperature 298.15 K. J. Chem. Thermodyn. 26, 797–802 (1994)

    Article  CAS  Google Scholar 

  34. Iglesias, T.P., Legido, J.L., Pereira, S.M., de Cominges, B., Paz Andrade, M.I.: Relative permittivities and refractive indices on mixing for (n-hexane + 1-pentanol, or 1-hexanol, or 1-heptanol) at T=298.15 K. J. Chem. Thermodyn. 32, 923–930 (2000)

    Article  CAS  Google Scholar 

  35. Jimenez, E., Franjo, C., Segade, L., Legido, J.L., Paz Andrade, M.I.: Excess molar volumes of ternary mixtures of {x 1CH3CH2COOCH2CH3+x 2CH3(CH2)4CH3+(1−x 1−x 2)CH3(CH2)6OH or CH3(CH2)7OH} at the temperature of 298.15 K. J. Chem. Eng. Data 42, 262–265 (1997)

    Article  CAS  Google Scholar 

  36. Jimenez, E., Casas, H., Segade, L., Franjo, C.: Surface tensions, refractive indexes and excess molar volumes of hexane + 1-alkanol mixtures at 298.15 K. J. Chem. Eng. Data 45, 862–866 (2000)

    Article  CAS  Google Scholar 

  37. Kasprzycka-Guttman, T., Wilczura, H.: Thermodynamic properties of binary mixtures pyridine base and iso-aliphatic alcohols. Acta Chim. Hung. 116, 77–80 (1984)

    CAS  Google Scholar 

  38. Kaur, H., Samra, N.-S., Mahl, B.-S., Khurma, J.-R., Bender, M., Heintz, A.: Excess volumes of binary liquid mixtures of n-alkanols and cycloalkanols with n-alkanes and the theoretical treatment using the ERAS-model. Fluid Phase Equilib. 67, 241–257 (1991)

    Article  CAS  Google Scholar 

  39. Kiyohara, O., Benson, G.C.: Ultrasonic speeds and isentropic compressibilities of n-alkanol + n-heptane mixtures at 298.15 K. J. Chem. Thermodyn. 11, 861–873 (1979)

    Article  CAS  Google Scholar 

  40. Klofutar, C., Nemec, T.: Apparent molar volumes and expansibilities of 1-octanol, 1-nonanol, and 1-decanol in dilute cyclohexane solutions. J. Solution Chem. 25, 1151–1162 (1996)

    Article  CAS  Google Scholar 

  41. Kulikov, D., Verevkin, S.P., Heintz, A.: Enthalpies of vaporization of a series of aliphatic alcohols. Experimental results and values predicted by the ERAS model. Fluid Phase Equilib. 192, 187–207 (2001)

    Article  CAS  Google Scholar 

  42. Lara, J., Desnoyers, J.E.: Isentropic compressibilities of alcohol-water mixtures at 25 °C. J. Solution Chem. 10, 465–478 (1981)

    Article  CAS  Google Scholar 

  43. Lorenzi, L., Fermeglia, M., Torniano, G.: Densities and viscosities of 1,1,1-trichloroethane with 13 different solvents at 298.15 K. J. Chem. Eng. Data 40, 1172–1177 (1995)

    Article  CAS  Google Scholar 

  44. Lubowiecka, B.: Wolumetryczne, akustyczne i wiskozymetryczne badania binarnych mieszanin etano-1,2-diol + nonan-1-ol. M.A. Thesis, University of Silesia, Katowice (2003)

  45. Marczak, W., Dzida, M., Ernst, S.: Determination of the thermodynamic properties of 1-propanol and 1-hexanol from speed of sound measurements under elevated pressures. High Temp. High Pres. 32, 283–292 (2000)

    Article  CAS  Google Scholar 

  46. Mascato, E., Mosteiro, L., Pineiro, M.M., Garcia, J., Iglesias, T.P., Legido, J.L.: Thermodynamic properties on mixing for hexane + cyclohexane + 1-octanol at 298.15 K. J. Chem. Eng. Data 45, 1154–1159 (2000)

    Article  CAS  Google Scholar 

  47. Mehta, S.K., Chauchan, R.K.: Ultrasonic velocity and apparent isentropic compressibilities in mixtures of nonelectrolytes. J. Solution Chem. 26, 295–308 (1997)

    Article  CAS  Google Scholar 

  48. Minh, D.C., Ruel, M.: Total pressure method. Binary systems cyclohexane-1-pentanol, -1-heptanol, and -1-octanol. J. Chem. Eng. Data 18, 41–44 (1973)

    Article  Google Scholar 

  49. Nagata, I., Ohta, T., Uchiyarna, Y.: Excess Gibbs free energies for binary systems. Isopropyl alcohol with benzene, cyclohexane, methylcyclohexane. J. Chem. Eng. Data 18, 54–59 (1973)

    Article  CAS  Google Scholar 

  50. Ortega, J., Garcia, J.D.: Excess molar volumes of methyl alkanoate with n-alkanols at 298.15 K. Can. J. Chem. 66, 1520–1524 (1988)

    CAS  Google Scholar 

  51. Orwoll, R.A., Flory, P.J.: Thermodynamic properties of binary mixtures of n-alkanes. J. Am. Chem. Soc. 89, 6822–6829 (1967)

    Article  CAS  Google Scholar 

  52. Pal, A., Das, G.: Excess molar volumes and excess partial molar volumes of triethylene glycol monoethyl ether–n-alcohol mixtures at 25 °C. J. Solution Chem. 28, 237–246 (1999)

    Article  CAS  Google Scholar 

  53. Piñeiro, A.: Excess volumes and isobaric heat capacities of diisopropyl ether with several alkanols at 298.15 K. Application of the symmetrical extended real associated solution model. Fluid Phase Equilib. 216, 245–256 (2004)

    Article  Google Scholar 

  54. Piñeiro, A., Amigo, A., Bravo, R., Brocos, P.: Re-examination and symmetrization of the adjustable parameters of the ERAS model. Review on its formulation and application. Fluid Phase Equilib. 173, 211–239 (2000)

    Article  Google Scholar 

  55. Piñeiro, A., Brocos, P., Amigo, A., Pintos, M., Bravo, R.: Refractive indexes of binary mixtures of tetrahydrofuran with 1-alkanols at 25 °C and temperature dependence of n and ρ for the pure liquids. J. Solution Chem. 31, 369–380 (2002)

    Article  Google Scholar 

  56. Polak, J., Murakami, S., Benson, G.C., Pflug, H.S.: Excess enthalpy, volume, and Gibbs free energy of n-propanol–isopropanol mixtures at 25 °C. Can. J. Chem. 48, 3782–3785 (1970)

    Article  CAS  Google Scholar 

  57. Riddick, J.A., Bunger, W.B., Sakano, T.K.: Organic Solvents, 4th edn. Techniques of Chemistry, vol. II. Wiley, New York (1986)

    Google Scholar 

  58. Ritzoulis, G.: Excess properties of the binary liquid systems dimethyl sulfoxide + isopropanol and propylene carbonate + isopropanol. Can. J. Chem. 67, 1105–1108 (1989)

    Article  CAS  Google Scholar 

  59. Rodriguez, A., Canosa, J., Tojo, J.: Density, refractive index, and speed of sound of binary mixtures (diethyl carbonate plus alcohols) at several temperatures. J. Chem. Eng. Data 46, 1506–1515 (2001)

    Article  CAS  Google Scholar 

  60. Sakurai, M., Nakamura, K., Takenaka, S.: Apparent molar volumes and apparent molar adiabatic compressions of water in some alcohols. Bull. Chem. Soc. Japan 67, 352–359 (1994)

    Article  CAS  Google Scholar 

  61. Santana, P., Balseiro, J., Salgado, J., Paz Andrade, M.I.: Excess molar enthalpies and excess molar volumes of binary systems containing {xCH3(CH2)7CI+(1−x)CH3(CH2) n−10} (n=4 to 8) at T=298.15 K. J. Chem. Thermodyn. 31, 1329–1337 (1999)

    Article  CAS  Google Scholar 

  62. Savaroglu, G., Aral, E.: Speeds of sound and isentropic compressibilities in binary mixtures of 2-propanol with several 1-alkanols at 298.15 K. Int. J. Thermophys. 26, 1525–1535 (2005)

    Article  CAS  Google Scholar 

  63. Singh, J., Pflug, H.D., Benson, G.C.: Excess thermodynamic properties of isopropanol–n-decanol mixtures. Can. J. Chem. 47, 543–546 (1969)

    Article  CAS  Google Scholar 

  64. Tanaka, R., Toyama, S., Murakami, S.: Heat capacities of {xC n H2n+1OH + (1−x)C7H16} for n=1 to 6) at 298.15 K. J. Chem. Thermodyn. 18, 63–73 (1986)

    Article  CAS  Google Scholar 

  65. Villa, S., Riesco, N., Garcia de la Fuente, I., González, J.A., Cobos, J.C.: Thermodynamics of mixtures with strongly negative deviations from Raoult’s Law. VII. Excess molar volumes at 25 °C for 1-alkanol + N-methylbutylamine systems—characterization in terms of the ERAS model. J. Solution Chem. 32, 179–194 (2003)

    Article  CAS  Google Scholar 

  66. Węgrzyn, P.: Akustyczne i termodynamiczne badania binarnych mieszanin alkoholi jednowodorotlenowych. M.A. Thesis, University of Silesia, Katowice (2003)

  67. Yanes, C., Maestre, A., Perez-Tejeda, P., Calvente, J.J.: Excess molar volumes and refractive-indexes of cis-9-octadecenoic acid plus N-alkanes or alkan-1-ols at 298.15 K. J. Chem. Eng. Data 38, 512–515 (1993)

    Article  CAS  Google Scholar 

  68. Zorębski, E., Zorębski, M., Ernst, S.: A pulse-echo-overlap system for ultrasound velocity measurements in liquids. Testing and discussions of the errors. Papers of the World Congress on Ultrasonics, pp. 547–550, Berlin (1995)

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  1. Institute of Chemistry, University of Silesia, Szkolna 9, 40-006, Katowice, Silesia, Poland

    Monika Geppert-Rybczyńska, Barbara Hachuła & Monika Bucek

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  1. Monika Geppert-Rybczyńska
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  2. Barbara Hachuła
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Geppert-Rybczyńska, M., Hachuła, B. & Bucek, M. Theoretical Description of Excess Molar Functions in the Case of Very Small Excess Values. Investigation of Excess Molar Volumes of Propan-2-ol + Alkanol Mixtures. J Solution Chem 37, 1747–1773 (2008). https://doi.org/10.1007/s10953-008-9334-7

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