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The Development of the Theory of Strong Electrolyte Solutions

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Abstract

The expression for Gibbs energy of electrolyte solutions has been derived taking into account the contribution of interactions of the hydrated shells of ions. It is in good agreement with data for the dependence of the hydration number on concentration. The contribution of different interactions to the activity coefficient depending on concentration has been analyzed. The possibility of determining parameters which characterize the composition of hydrated shells of individual atoms from experimental data has been considered.

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Authors and Affiliations

  1. Ivanovo State University, Ermaka Ul. 38, 153035, Ivanovo, Russia

    Alexandr A. Zaitsev

  2. Institute of Solution Chemistry, Russian Academy of Sciences, Akademicheskaya Ul. 1, 153045, Ivanovo, Russia

    Vladimir N. Afanasiev

Authors
  1. Alexandr A. Zaitsev
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  2. Vladimir N. Afanasiev
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Correspondence to Vladimir N. Afanasiev.

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Zaitsev, A.A., Afanasiev, V.N. The Development of the Theory of Strong Electrolyte Solutions. J Solution Chem 37, 1425–1436 (2008). https://doi.org/10.1007/s10953-008-9312-0

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  • DOI: https://doi.org/10.1007/s10953-008-9312-0

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