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Micellar Catalysis on Pentavalent Vanadium Ion Oxidation of D-Sorbitol in Aqueous Acid Media: A Kinetic Study

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Abstract

Vanadium(V) oxidation of D-sorbitol shows a first-order dependency on the concentrations of D-sorbitol, vanadium(V), H+ and HSO −4 . These observations remain unaltered in the presence of externally added surfactants. The effects of the cationic surfactant (i.e., CPC), anionic surfactant (i.e., SDS) and neutral surfactant (i.e., TX-100) have been studied. CPC inhibits the reactions whereas SDS and TX-100 accelerate the reaction to different extents. SDS and TX-100 can be used as catalysts in the production of D-glucose from D-sorbitol.

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Authors and Affiliations

  1. Department of Chemistry, The University of Burdwan, Golapbag, Burdwan, 713104, WB, India

    Bidyut Saha, Kiran M. Chowdhury & Jayashree Mandal

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  1. Bidyut Saha
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  2. Kiran M. Chowdhury
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  3. Jayashree Mandal
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Correspondence to Bidyut Saha.

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Saha, B., Chowdhury, K.M. & Mandal, J. Micellar Catalysis on Pentavalent Vanadium Ion Oxidation of D-Sorbitol in Aqueous Acid Media: A Kinetic Study. J Solution Chem 37, 1321–1328 (2008). https://doi.org/10.1007/s10953-008-9304-0

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