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Volumetric, Viscosity and Self-Diffusion Coefficient Studies of [18-Crown-6:M]A Complexed Species in Water at 298.15 K

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Abstract

Density and viscosity measurements were made for aqueous solutions of electrolytes containing 18-crown-6 (18C6) at 298.15 K. A method is proposed to extract the volumetric and viscosity data of the [18C6:M]A complexed species in aqueous solutions from ternary mixtures using the thermodynamic equilibrium constant values at 298.15 K. The apparent molar volume of the [18C6:M]A complexed species have been estimated for these binary solutions. Further, the viscosity data thus obtained were subjected to analysis using the Jones-Dole equation to get viscosity A- and B-coefficients of complexed ions in water. The hydration number and molecular radius of the hydrated complexes in water have been estimated. It was observed that hydration of the complexed ion is strongly influenced by the charge density of the metal ions in the complexed state. The self-diffusion coefficient and correlation time values for the complexes in water were calculated using viscosity data, which indicated that diffusion of complexed species was faster than that of the host ligand 18C6 (D3d structural entity) in water at 298.15 K. It was suggested that the ionic radii estimated in this work for large hydrophobic cations can be of use in studying electrostatic and hydrophobic interactions especially in aqueous solutions.

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  1. Department of Chemistry, Shivaji University, Kolhapur, 416 004, India

    Dilip H. Dagade, Rajendra R. Kumbhar & Kesharsingh J. Patil

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Dagade, D.H., Kumbhar, R.R. & Patil, K.J. Volumetric, Viscosity and Self-Diffusion Coefficient Studies of [18-Crown-6:M]A Complexed Species in Water at 298.15 K. J Solution Chem 37, 265–282 (2008). https://doi.org/10.1007/s10953-007-9227-1

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