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Excess Molar Volumes, Viscosities and Speeds of Sound of the Ternary Mixture 1-Heptanol (1) + Tetrachloroethylene (2) + Methylcyclohexane (3) at 298.15 K

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Abstract

Densities (ρ), viscosities (η) and speeds of sound (u) of the ternary mixture (1-heptanol + tetrachloroethylene + methylcyclohexane) and the corresponding binary mixtures (1-heptanol + tetrachloroethylene), (1-heptanol + methylcyclohexane) and (tetrachloroethylene + methylcyclohexane) at 298.15 K were measured over the whole composition range. The data obtained are used to calculate the excess molar volumes (V E), excess isobaric thermal expansivities (α E), viscosity deviations (Δη), excess Gibbs energies of activation of viscous flow (ΔG *E) and excess isentropic compressibilities (κ E S ) of the binary and ternary mixtures. The data from the binary systems were fitted by the Redlich–Kister equation whereas the best correlation method for the ternary system was found using the Nagata equation. Viscosities, speeds of sound and isentropic compressibilities of the binary and ternary mixtures have been correlated by means of several empirical and semi-empirical equations. The best correlation method for viscosities of binary systems is found using the Iulan et al. equation and for the ternary system using the Heric and McAllister equations. The best correlation method for the speeds of sound and isentropic compressibilities of the binary system (1-heptanol + methylcyclohexane) is found using IMR (Van Deal ideal mixing relation) and for the binary system (tetrachloroethylene + methylcyclohexane) it is found using the NR (Nomoto relation) and for the binary system (1-heptanol + tetrachloroethylene) and the ternary system (1-heptanol + trichloroethylene + methylcyclohexane) it is obtained from the FLT (Jacobson free length theory).

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References

  1. Iloukhani, H., Samiey, B., Moghaddasi, M.A.: Speeds of sound, isentropic compressibilities, viscosities and excess molar volumes of binary mixtures of methylcyclohexane + 2-alkanols or ethanol at T=298.15 K. J. Chem. Thermodyn. 38, 190–200 (2006)

    Article  CAS  Google Scholar 

  2. Iloukhani, H., Zarei, H.A.: Excess molar enthalpies of N,N-dimethylformamide + alkan-1-ols (C1–C6) at 298.15 K. J. Chem. Eng. Data 47, 195–197 (2002)

    Article  CAS  Google Scholar 

  3. Iloukhani, H., Samiey, B.: Studies of viscosities and excess molar volumes of the binary mixtures of 1-heptanol + 1,2-dichloroethane, + 1,1,1-trichloroethane, + trichloroethylene and tetrachloroethylene at (293.15, 298.15, and 303.15) K for the liquid region and at ambient pressure. J. Chem. Eng. Data 50, 1911–1916 (2005)

    Article  CAS  Google Scholar 

  4. Zarei, H.A., Iloukhani, H.: Excess molar enthalpies of formamide + some alkan-1-ols (C1–C8) and their correlations at 298.15 K. Thermochim. Acta 405, 123–128 (2003)

    Article  CAS  Google Scholar 

  5. Iloukhani, H., Rezaei-Sameti, M.: Excess molar volumes of the ternary system {methylcyclohexane (1) + cyclohexane (2) + n-alkanes (3)} at T=298.15 K. J. Chem. Thermodyn. 37, 1151–1161 (2005)

    Article  CAS  Google Scholar 

  6. Redlich, O.J., Kister, A.T.: Thermodynamics of nonelectrolytic solutions. Algebraic representation of thermodynamic properties and the classification of solutions. Ind. Eng. Chem. 40, 345–348 (1948)

    Article  Google Scholar 

  7. Cibulka, I.: Estimation of excess volume and density of ternary liquid mixtures of nonelectrolytes from binary data. Collect. Czech. Chem. Commun. 47, 1414–1419 (1982)

    CAS  Google Scholar 

  8. Olive, F., Patil, K.R., Fernandez, J., Coronas, A.: Excess volumes and viscosities of the ternary system water-trifluoroethanol-tetraethylene glycol dimethyl ether at 303.15 K. Thermochim. Acta 259, 57–70 (1995)

    Article  CAS  Google Scholar 

  9. Nagata, I., Tamura, K.: Excess molar enthalpies of {methanol or ethanol + (2-butanone + benzene)} at 298.15 K. J. Chem. Thermodyn. 22, 279–283 (1990)

    Article  CAS  Google Scholar 

  10. Grunberg, L., Nissan, A.H.: The viscosities of liquid mixtures. Trans. Faraday Soc. 45, 125–137 (1949)

    Article  CAS  Google Scholar 

  11. Dominguez, M., Pardo, J.I., Gascon, I.G., Royo, F.M., Urieta, J.S.: Viscosities of the ternary mixture (2-butanol + n-hexane + 1-butylamine) at 298.15 and 313.15 K. Fluid Phase Equilib. 169, 277–292 (2000)

    Article  CAS  Google Scholar 

  12. Canosa, J., Rodriguez, A., Tojo, J.: Dynamic viscosity and speed of sound of the ternary mixture methyl acetate + methanol + ethanol at 298.15 K. J. Chem. Eng. Data 43, 961–966 (1998)

    Article  CAS  Google Scholar 

  13. Hind, R.K., McLaughlin, E., Ubbelohde, A.R.: Structure and viscosity of liquids. Camphor + pyrene mixtures. Trans. Faraday Soc. 56, 328–330 (1960)

    Article  CAS  Google Scholar 

  14. Hind, R.K., McLaughlin, E., Ubbelohde, A.R.: Structure and viscosity of liquids. Viscosity–temperature relationships of pyrrole and pyrrolidine. Trans. Faraday Soc. 56, 331–334 (1960)

    Article  CAS  Google Scholar 

  15. Katti, P.K., Chaudhri, M.M.: Viscosities of binary mixtures of benzyl acetate with dioxane, aniline and m-cresol. J. Chem. Eng. Data 9, 442–443 (1964)

    Article  CAS  Google Scholar 

  16. McAllister, R.A.: The viscosities of liquid mixtures. AIChE J. 6, 427–431 (1960)

    Article  CAS  Google Scholar 

  17. Heric, E.L.: The viscosity of ternary mixtures. J. Chem. Eng. Data 11, 66–68 (1966)

    Article  CAS  Google Scholar 

  18. Frenkel, Y.I.: Kinematic Theory of Liquids. Oxford University Press, London (1946)

    Google Scholar 

  19. Iulan, O., Iulita, M.C., Loresco, G.: 11th International Congress of Chemical Engineering, Chemical Equipment Design and Automation, CHISA93, Prague, Czech Republic, August 29–September 3, paper F2-386 (1993)

  20. Jacobson, B.: Intermolecular free lengths in the liquid state. 1. Adiabatic and isothermal compressibilities. Acta Chem. Scand. A 6, 1485–1498 (1952)

    CAS  Google Scholar 

  21. Savaroglu, G., Aral, E.: Densities, speeds of sound and isentropic compressibilities of the ternary mixture 2-propanol + acetone + cyclohexane and the constituent binary mixtures at 298.15 and 303.15 K. Fluid Phase Equilib. 215, 253–262 (2004)

    Article  CAS  Google Scholar 

  22. Oswal, S.L., Patel, S.G., Gradas, R.L., Ghael, N.Y.: Speeds of sound and isentropic compressibilities of binary mixtures containing trialkylamines with alkanes and mono-alkylamines at 303.15–313.15 K. Fluid Phase Equilib. 215, 61–70 (2004)

    Article  CAS  Google Scholar 

  23. Sastry, N.Y., Patel, M.C., Patel, S.R.: Ultrasonic behaviour of methylmethacrylate + hydrocarbon mixtures at 298.15 and 308.15 K. Fluid Phase Equilib. 155, 261–275 (1999)

    Article  CAS  Google Scholar 

  24. Schaaff, W.: Molekularakustic. Springer, Berlin (1963)

    Google Scholar 

  25. Nomoto, O.: Empirical formula for sound velocity in liquid mixtures. J. Phys. Soc. Jpn. 13, 1528 (1958)

    Article  ADS  CAS  Google Scholar 

  26. Junjie, Z.: J. Chem. Univ. Sci. Technol. 14, 298 (1984)

    Google Scholar 

  27. Van Deal, W., Vageel, E.: Proceedings of the First International Conference on Calorimetry and Thermodynamics, Warsaw (1969)

  28. Handbook of Chemistry and Physics, 81st edn., CRC Press, Boca Raton (2000), Section 6, pp. 170–174

  29. Kretschmer, C., Wiebe, R.: Liquid-vapor equilibrium of ethanol-methylcyclohexane solutions. J. Am. Chem. Soc. 71, 3176–3179 (1949)

    Article  CAS  Google Scholar 

  30. Shinomiya, T.: Dielectric dispersion and intermolecular association for 28 pure liquid alcohols. The position dependence of hydroxyl group in the hydrocarbon chain. Bull. Chem. Soc. Jpn. 62, 908–914 (1989)

    Article  CAS  Google Scholar 

  31. Handbook of Chemistry and Physics, 81st edn., CRC Press, Boca Raton (2000), Section 5, pp. 5–60

  32. Francesconi, R., Comelli, F.: Excess molar enthalpies of binary mixtures containing dimethylcarbonate, diethylcarbonae or propylene carbonate + three chloroalkanes at 298.15 K. Thermochim. Acta 260, 95–103 (1995)

    Article  CAS  Google Scholar 

  33. Benson, G.C., Kiyohara, O.: Evaluation of excess isentropic compressibilities and isochoric heat capacities. J. Chem. Thermodyn. 11, 1061–1064 (1979)

    Article  CAS  Google Scholar 

  34. Ben-Naiem, A.: Water and Aqueous Solutions. Plenum Press, New York (1974)

    Google Scholar 

  35. Kauzman, W., Eyring, H.: The viscous flow of large molecules. J. Am. Chem. Soc. 62, 3113–3125 (1940)

    Article  Google Scholar 

  36. Vogel, H., Weiss, A.: Transport properties of liquids, III. Viscosity of athermal liquid mixtures. Ber. Bunsenges. Phys. Chem. 86, 193–198 (1982)

    CAS  Google Scholar 

  37. Meyer, R., Meyer, M., Metzger, J., Peneloux, A.: Thermodynamic study of binary mixtures. II Study of the liquid-phase interactions between pyridine bases and carbon tetrachloride by measuring the viscosity coefficients. J. Chim. Phys. Physicochim. Biol. 68, 406–412 (1971)

    CAS  Google Scholar 

  38. Fort, R.J., Moore, W.R.: Viscosities of binary liquid mixtures. Trans. Faraday Soc. 62, 1112–1119 (1966)

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, University of Bu-Ali Sina, Hamadan, Iran

    H. Iloukhani

  2. Department of Chemistry, Faculty of Science, University of Lorestan, Khoramabad, Iran

    B. Samiey

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  1. H. Iloukhani
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  2. B. Samiey
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Iloukhani, H., Samiey, B. Excess Molar Volumes, Viscosities and Speeds of Sound of the Ternary Mixture 1-Heptanol (1) + Tetrachloroethylene (2) + Methylcyclohexane (3) at 298.15 K. J Solution Chem 36, 691–714 (2007). https://doi.org/10.1007/s10953-007-9143-4

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